dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)
Names
[ CAS No. ]:
905459-27-0
[ Name ]:
dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)
[Synonym ]:
1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole,3-chloropyridine,dichloropalladium
Chemical & Physical Properties
[ Melting Point ]:
240℃ (DEC.)
[ Molecular Formula ]:
C32H42Cl3N3Pd
[ Molecular Weight ]:
681.475
[ Exact Mass ]:
679.147888
[ PSA ]:
19.37000
[ LogP ]:
3.80850
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H312-H332
[ Precautionary Statements ]:
P280
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
20/21/22
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
28439000
Articles
Chemistry 12 , 4749, (2006)
We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ...
Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)
Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...
Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.Chemistry 14 , 2443, (2008)
Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...