(Pentafluorophenyl)hydrazine

Modify Date: 2024-01-10 18:53:19

(Pentafluorophenyl)hydrazine Structure
(Pentafluorophenyl)hydrazine structure
Common Name (Pentafluorophenyl)hydrazine
CAS Number 828-73-9 Molecular Weight 198.093
Density 1.7±0.1 g/cm3 Boiling Point 117.6±40.0 °C at 760 mmHg
Molecular Formula C6H3F5N2 Melting Point 74-76 °C(lit.)
MSDS Chinese USA Flash Point 24.9±27.3 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name pentafluorophenylhydrazine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 117.6±40.0 °C at 760 mmHg
Melting Point 74-76 °C(lit.)
Molecular Formula C6H3F5N2
Molecular Weight 198.093
Flash Point 24.9±27.3 °C
Exact Mass 198.021637
PSA 38.05000
LogP 2.53
Vapour Pressure 17.3±0.2 mmHg at 25°C
Index of Refraction 1.505
Storage condition -20°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MV8325000
CHEMICAL NAME :
Hydrazine, (pentafluorophenyl)-
CAS REGISTRY NUMBER :
828-73-9
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H3-F5-N2
MOLECULAR WEIGHT :
198.11
WISWESSER LINE NOTATION :
ZMR BF CF DF EF FF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03414

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36-S24/25
RIDADR 2811
WGK Germany 3
RTECS MV8325000
HS Code 2928000090

 Synthetic Route

~83%

(Pentafluorophenyl)hydrazine Structure

(Pentafluorophe...

CAS#:828-73-9

Literature: Pharmazie, , vol. 36, # 5 p. 336 - 337 Heterocycles, , vol. 16, # 1 p. 71 - 76

~68%

(Pentafluorophenyl)hydrazine Structure

(Pentafluorophe...

CAS#:828-73-9

Literature: Journal of the Chemical Society, , p. 4966 - 4976 Journal of the Chemical Society, , p. 1768 - 1771 GB1054622 , ; C.A., , vol. 67, p. 21597

~24%

Detail
Literature: Journal of Organic Chemistry, , vol. 29, p. 1562 - 1565 US3440277 , ; C.A., , vol. 71, p. 30199

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Articles11

More Articles
Application of pentafluorophenyl hydrazine derivatives to the analysis of nabumetone and testosterone in human plasma by liquid chromatography-atmospheric pressure chemical ionization-tandem mass spectrometry.

Anal. Bioanal. Chem 380(7-8) , 891-7, (2004)

Two carbonyl compounds, nabumetone and testosterone, were derivatized with pentafluorophenyl hydrazine (PFPH) and analyzed by atmospheric-pressure chemical-ionization mass spectrometry. The PFPH deriv...

Comparison of extraction methods and detection systems in the gas chromatographic analysis of volatile carbonyl compounds.

J. Chromatogr. A. 779(1-2) , 360-9, (1997)

High-resolution gas chromatography (HRGC) with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), flame ionization detection (FID) or with mass spectrometry-selected ion monitoring...

Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC–MS and its comparison with HPLC method

Talanta 85(1) , 406-14, (2011)

The classical analytical method for gaseous carbonyl measurements based on solid sorbent coated with 2,4-dinitrophenylhydrazine (DNPH) and analysis by HPLC/UV suffers from limited resolution of carbon...

 Synonyms

Pentafluorophenyl hydrazine
(Pentafluorophenyl)hydrazine
ZMR BF CF DF EF FF
2,3,4,5,6-Pentafluorophenylhydrazine
EINECS 212-586-7
Hydrazine, (2,3,4,5,6-pentafluorophenyl)-
Pentafluorophenylhydrazine
MFCD00007574
1-(2,3,4,5,6-Pentafluorophenyl)hydrazine
(2,3,4,5,6-pentafluorophenyl)hydrazine