(Pentafluorophenyl)hydrazine
Names
[ CAS No. ]:
828-73-9
[ Name ]:
(Pentafluorophenyl)hydrazine
[Synonym ]:
Pentafluorophenyl hydrazine
(Pentafluorophenyl)hydrazine
ZMR BF CF DF EF FF
2,3,4,5,6-Pentafluorophenylhydrazine
EINECS 212-586-7
Hydrazine, (2,3,4,5,6-pentafluorophenyl)-
Pentafluorophenylhydrazine
MFCD00007574
1-(2,3,4,5,6-Pentafluorophenyl)hydrazine
(2,3,4,5,6-pentafluorophenyl)hydrazine
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
117.6±40.0 °C at 760 mmHg
[ Melting Point ]:
74-76 °C(lit.)
[ Molecular Formula ]:
C6H3F5N2
[ Molecular Weight ]:
198.093
[ Flash Point ]:
24.9±27.3 °C
[ Exact Mass ]:
198.021637
[ PSA ]:
38.05000
[ LogP ]:
2.53
[ Vapour Pressure ]:
17.3±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.505
[ Storage condition ]:
-20°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- MV8325000
- CHEMICAL NAME :
- Hydrazine, (pentafluorophenyl)-
- CAS REGISTRY NUMBER :
- 828-73-9
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C6-H3-F5-N2
- MOLECULAR WEIGHT :
- 198.11
- WISWESSER LINE NOTATION :
- ZMR BF CF DF EF FF
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 180 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03414
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36-S24/25
[ RIDADR ]:
2811
[ WGK Germany ]:
3
[ RTECS ]:
MV8325000
[ HS Code ]:
2928000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2928000090
[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
Anal. Bioanal. Chem 380(7-8) , 891-7, (2004)
Two carbonyl compounds, nabumetone and testosterone, were derivatized with pentafluorophenyl hydrazine (PFPH) and analyzed by atmospheric-pressure chemical-ionization mass spectrometry. The PFPH deriv...
Comparison of extraction methods and detection systems in the gas chromatographic analysis of volatile carbonyl compounds.J. Chromatogr. A. 779(1-2) , 360-9, (1997)
High-resolution gas chromatography (HRGC) with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), flame ionization detection (FID) or with mass spectrometry-selected ion monitoring...
Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC–MS and its comparison with HPLC methodTalanta 85(1) , 406-14, (2011)
The classical analytical method for gaseous carbonyl measurements based on solid sorbent coated with 2,4-dinitrophenylhydrazine (DNPH) and analysis by HPLC/UV suffers from limited resolution of carbon...