(Pentafluorophenyl)hydrazine

Names

[ CAS No. ]:
828-73-9

[ Name ]:
(Pentafluorophenyl)hydrazine

[Synonym ]:
Pentafluorophenyl hydrazine
(Pentafluorophenyl)hydrazine
ZMR BF CF DF EF FF
2,3,4,5,6-Pentafluorophenylhydrazine
EINECS 212-586-7
Hydrazine, (2,3,4,5,6-pentafluorophenyl)-
Pentafluorophenylhydrazine
MFCD00007574
1-(2,3,4,5,6-Pentafluorophenyl)hydrazine
(2,3,4,5,6-pentafluorophenyl)hydrazine

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
117.6±40.0 °C at 760 mmHg

[ Melting Point ]:
74-76 °C(lit.)

[ Molecular Formula ]:
C₆H₃F₅N₂

[ Molecular Weight ]:
198.093

[ Flash Point ]:
24.9±27.3 °C

[ Exact Mass ]:
198.021637

[ PSA ]:
38.05000

[ LogP ]:
2.53

[ Vapour Pressure ]:
17.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.505

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MV8325000

CHEMICAL NAME :: Hydrazine, (pentafluorophenyl)-

CAS REGISTRY NUMBER :: 828-73-9

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C6-H3-F5-N2

MOLECULAR WEIGHT :: 198.11

WISWESSER LINE NOTATION :: ZMR BF CF DF EF FF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03414

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
MV8325000

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Application of pentafluorophenyl hydrazine derivatives to the analysis of nabumetone and testosterone in human plasma by liquid chromatography-atmospheric pressure chemical ionization-tandem mass spectrometry.

Anal. Bioanal. Chem 380(7-8) , 891-7, (2004)

Two carbonyl compounds, nabumetone and testosterone, were derivatized with pentafluorophenyl hydrazine (PFPH) and analyzed by atmospheric-pressure chemical-ionization mass spectrometry. The PFPH deriv...

Comparison of extraction methods and detection systems in the gas chromatographic analysis of volatile carbonyl compounds.

J. Chromatogr. A. 779(1-2) , 360-9, (1997)

High-resolution gas chromatography (HRGC) with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), flame ionization detection (FID) or with mass spectrometry-selected ion monitoring...

Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC–MS and its comparison with HPLC method

Talanta 85(1) , 406-14, (2011)

The classical analytical method for gaseous carbonyl measurements based on solid sorbent coated with 2,4-dinitrophenylhydrazine (DNPH) and analysis by HPLC/UV suffers from limited resolution of carbon...

Related Compounds

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