(2-Bromo-2-propen-1-yl)(trimethyl)silane

Modify Date: 2024-01-10 11:32:14

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure
(2-Bromo-2-propen-1-yl)(trimethyl)silane structure
 Common Name (2-Bromo-2-propen-1-yl)(trimethyl)silane
CAS Number 81790-10-5 Molecular Weight 193.157
Density 1.1±0.1 g/cm3 Boiling Point 145.4±23.0 °C at 760 mmHg
Molecular Formula C6H13BrSi Melting Point N/A
MSDS N/A Flash Point 42.6±17.6 °C

 Names

Name (2-Bromoallyl)trimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 145.4±23.0 °C at 760 mmHg
Molecular Formula C6H13BrSi
Molecular Weight 193.157
Flash Point 42.6±17.6 °C
Exact Mass 191.996979
LogP 3.71
Vapour Pressure 6.1±0.3 mmHg at 25°C
Index of Refraction 1.448

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases 10-36/37/38
Safety Phrases 16-26-36
RIDADR UN 1993 3/PG 3
Packaging Group III
Hazard Class 3.2

 Synthetic Route

METHYLMAGNESIUM BROMIDE structure

METHYLMAGNESIUM...

CAS#:75-16-1

2,3-Dibromopropene structure

2,3-Dibromopropene

CAS#:513-31-5

~70%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Gill, Duncan; Taylor, Nicholas H.; Thomas, Eric J. Tetrahedron, 2011 , vol. 67, # 27-28 p. 5034 - 5045
2,3-Dibromopropene structure

2,3-Dibromopropene

CAS#:513-31-5

~62%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Trost, Barry M.; Chan, Dominic M. T. Journal of the American Chemical Society, 1982 , vol. 104, # 13 p. 3733 - 3735
Acetic acid 2-bromo-2-propenyl ester structure

Acetic acid 2-b...

CAS#:63915-88-8

Tris(trimethylsilyl)aluminium structure

Tris(trimethyls...

CAS#:65343-66-0

~88%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Trost, Barry M.; Yoshida, Jun-ichi; Lautens, Mark Journal of the American Chemical Society, 1983 , vol. 105, # 13 p. 4494 - 4496
tetralithium,trimethylsilanide structure

tetralithium,tr...

CAS#:18000-27-6

2,3-Dibromopropene structure

2,3-Dibromopropene

CAS#:513-31-5

~67%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Smith, Janice Gorzynski; Quinn, Nina R.; Viswanathan, Malini Synthetic Communications, 1983 , vol. 13, # 1 p. 1 - 5
copper,trimethylsilicon structure

copper,trimethy...

CAS#:91899-54-6

2,3-Dibromopropene structure

2,3-Dibromopropene

CAS#:513-31-5

~92%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Smith, Janice Gorzynski; Drozda, Susan E.; Petraglia, Susan P.; Quinn, Nina R.; Rice, Elizabeth M.; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 22 p. 4112 - 4120
METHYLMAGNESIUM BROMIDE structure

METHYLMAGNESIUM...

CAS#:75-16-1

2-bromo-3-trichlorosilylprop-1-ene structure

2-bromo-3-trich...

CAS#:82415-86-9

~%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Tetrahedron Letters, , vol. 23, # 12 p. 1267 - 1270 Carbohydrate Research, , vol. 171, p. 223 - 232
Hexamethyldisilane structure

Hexamethyldisilane

CAS#:1450-14-2

2,3-Dibromopropene structure

2,3-Dibromopropene

CAS#:513-31-5

~%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Journal of the American Chemical Society, , vol. 113, # 19 p. 7350 - 7362
METHYLMAGNESIUM IODIDE structure

METHYLMAGNESIUM...

CAS#:917-64-6

2-bromo-3-trichlorosilylprop-1-ene structure

2-bromo-3-trich...

CAS#:82415-86-9

~62%

(2-Bromo-2-propen-1-yl)(trimethyl)silane Structure

(2-Bromo-2-prop...

CAS#:81790-10-5

Literature: Hollingworth, Gregory J.; Lee, Thomas V.; Sweeney Synthetic Communications, 1996 , vol. 26, # 6 p. 1117 - 1134

 Synonyms

Silane, (2-bromo-2-propen-1-yl)trimethyl-
MFCD00043054
(2-Bromoprop-2-en-1-yl)(trimethyl)silane
2-bromoprop-2-enyl(trimethyl)silane
(2-Bromo-2-propen-1-yl)(trimethyl)silane
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