a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate

Modify Date: 2024-01-13 19:01:19

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure
a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate structure
 Common Name a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate
CAS Number 80244-96-8 Molecular Weight 232.23000
Density 1.228g/cm3 Boiling Point 340.5ºC at 760mmHg
Molecular Formula C10H16O6 Melting Point N/A
MSDS N/A Flash Point 130.4ºC

 Names

Name (6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.228g/cm3
Boiling Point 340.5ºC at 760mmHg
Molecular Formula C10H16O6
Molecular Weight 232.23000
Flash Point 130.4ºC
Exact Mass 232.09500
PSA 74.22000
Index of Refraction 1.468

 Synthetic Route

1,2-O-Isopropylidene-a-D-xylofuranose structure

1,2-O-Isopropyl...

CAS#:20031-21-4
Acetyl chloride structure

Acetyl chloride

CAS#:75-36-5

~91%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Ishihara, Kazuaki; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1993 , vol. 58, # 15 p. 3791 - 3793
3-O-Acetyl-1,2-O-isopropyliden-α-D-xylofuranose structure

3-O-Acetyl-1,2-...

CAS#:59940-64-6

~%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: ANADYS PHARMACEUTICALS, INC.; HALEY, Gregory, J. Patent: WO2010/57103 A1, 2010 ; Location in patent: Page/Page column 13; 14 ;
1,2-O-Isopropylidene-a-D-xylofuranose structure

1,2-O-Isopropyl...

CAS#:20031-21-4
Acetyl chloride structure

Acetyl chloride

CAS#:75-36-5

~28%

3-O-Acetyl-1,2-O-isopropyliden-α-D-xylofuranose structure

3-O-Acetyl-1,2-...

CAS#:59940-64-6
a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Ishihara, Kazuaki; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1993 , vol. 58, # 15 p. 3791 - 3793
3,5,6-tri-O-acetyl-1,2-O-isopropylidene-α-D-xylofuranose structure

3,5,6-tri-O-ace...

CAS#:42927-45-7

~70%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Ishido, Yoshiharu; Sakairi, Nobuo; Sekiya, Masao; Nakazaki, Nobuo Carbohydrate Research, 1981 , vol. 97, p. 51 - 80
N/A structure

N/A

CAS#:126308-96-1

~66%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Nishida, Atsushi; Oishi, Satoshi; Yonemitsu, Osamu Chemical & Pharmaceutical Bulletin, 1989 , vol. 37, # 8 p. 2266 - 2268
acetic pivalic mixed anhydride structure

acetic pivalic ...

CAS#:7137-32-8
1,2-O-Isopropylidene-a-D-xylofuranose structure

1,2-O-Isopropyl...

CAS#:20031-21-4

~77%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Mota, Antonio J.; Robles, Rafael; De Cienfuegos, Luis Alvarez; Lamenca, Alberto Tetrahedron Letters, 2004 , vol. 45, # 17 p. 3349 - 3353
1,2-O-Isopropylidene-a-D-xylofuranose structure

1,2-O-Isopropyl...

CAS#:20031-21-4
ethyl acetate structure

ethyl acetate

CAS#:141-78-6

~22%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Rana, Surjit S.; Barlow, Joseph J.; Matta, Khushi L. Tetrahedron Letters, 1981 , vol. 22, # 50 p. 5007 - 5010
Ethanoic anhydride structure

Ethanoic anhydride

CAS#:108-24-7
1,2-O-Isopropylidene-a-D-xylofuranose structure

1,2-O-Isopropyl...

CAS#:20031-21-4

~%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8
Literature: Levene; Raymond Journal of Biological Chemistry, 1933 , vol. 102, p. 317,323 Journal of Biological Chemistry, 1934 , vol. 107, p. 75,78

 Synonyms

5-Acetyl-1,2-isopropylidene-alfa-D-xylofuranose
[(3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl acetate
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