4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate structure
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Common Name | 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate | ||
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| CAS Number | 80149-80-0 | Molecular Weight | 283.353 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 371.7±42.0 °C at 760 mmHg | |
| Molecular Formula | C12H17NO5Si | Melting Point | 35-40ºC | |
| MSDS | Chinese USA | Flash Point | 178.6±27.9 °C | |
| Name | 4-[2-(Trimethylsilyl)ethoxycarbonyloxy]nitrobenzene |
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| Synonym | More Synonyms |
| Density | 1.1±0.1 g/cm3 |
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| Boiling Point | 371.7±42.0 °C at 760 mmHg |
| Melting Point | 35-40ºC |
| Molecular Formula | C12H17NO5Si |
| Molecular Weight | 283.353 |
| Flash Point | 178.6±27.9 °C |
| Exact Mass | 283.087585 |
| PSA | 81.35000 |
| LogP | 3.75 |
| Appearance of Characters | Crystalline Powder | Pale yellow |
| Vapour Pressure | 0.0±0.8 mmHg at 25°C |
| Index of Refraction | 1.504 |
| InChIKey | ZAQWGGKIMQIVGM-UHFFFAOYSA-N |
| SMILES | C[Si](C)(C)CCOC(=O)Oc1ccc([N+](=O)[O-])cc1 |
| Storage condition | 2-8°C |
| Water Solubility | Slightly soluble in water. |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Safety Phrases | S22-S24/25 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2931900090 |
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~95%
4-Nitrophenyl 2... CAS#:80149-80-0 |
| Literature: Kim, Sang Woong; Hong, Chang Yong; Lee, Koo; Lee, Eun Ju; Koh, Jong Sung Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 7 p. 735 - 738 |
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~%
4-Nitrophenyl 2... CAS#:80149-80-0 |
| Literature: Journal of Organic Chemistry, , vol. 48, # 9 p. 1539 - 1541 |
| HS Code | 2931900090 |
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| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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Synthesis of 2-(trimethylsilyl)ethyloxycarbonylamino acids and their use in peptide chemistry.
Hoppe. Seylers. Z. Physiol. Chem. 362 , 1289, (1981) 2-(Trimethylsilyl)ethyl-4-nitrophenyl carbonate has been prepared as a new reagent for the introduction of the 2-(trimethylsilyl)ethyloxycarbonyl group into amino acids or amino acid derivatives. The ... |
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L.A. Carpino et al.
J. Chem. Soc. Chem. Commun. , 358, (1978)
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A. Rosowsky, J.E. Wright
J. Org. Chem. 54 , 5551, (1989)
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| 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate |
| EINECS 279-406-7 |
| (4-nitrophenyl) 2-trimethylsilylethyl carbonate |
| MFCD00042930 |
| Carbonic acid, 4-nitrophenyl 2-(trimethylsilyl)ethyl ester |