tert-butyl benzyloxycarbamate

Modify Date: 2024-01-08 12:18:25

tert-butyl benzyloxycarbamate Structure
tert-butyl benzyloxycarbamate structure
Common Name tert-butyl benzyloxycarbamate
CAS Number 79722-21-7 Molecular Weight 223.268
Density 1.1±0.1 g/cm3 Boiling Point N/A
Molecular Formula C12H17NO3 Melting Point 45-47ºC(lit.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Tert-Butyl N-(Benzyloxy)Carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Melting Point 45-47ºC(lit.)
Molecular Formula C12H17NO3
Molecular Weight 223.268
Exact Mass 223.120850
PSA 47.56000
LogP 3.18
Index of Refraction 1.505
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2924299090

 Synthetic Route

~97%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: Bongim; Cardillo; Gentilucci; Tomasini Journal of Organic Chemistry, 1997 , vol. 62, # 26 p. 9148 - 9159

~10%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE MEDICALE (INSERM); GUICHOU, Jean-Francois; COLLIANDRE, Lionel; AHMED-BELKACEM, Hakim; PAWLOTSKY, Jean-Michel Patent: WO2011/76784 A2, 2011 ; Location in patent: Page/Page column 96-97 ;

~91%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: Kadi, Nadia; Arbache, Simon; Song, Lijiang; Oves-Costales, Daniel; Challis, Gregory L. Journal of the American Chemical Society, 2008 , vol. 130, # 32 p. 10458 - 10459

~99%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: Ortho Pharmaceutical Corporation Patent: US5066658 A1, 1991 ; US 5066658 A

~98%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: Sulsky, Richard; Demers, James P. Tetrahedron Letters, 1989 , vol. 30, p. 31 - 34

~%

tert-butyl benzyloxycarbamate Structure

tert-butyl benz...

CAS#:79722-21-7

Literature: Chemical Communications, , # 11 p. 975 - 976

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles2

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Structural determinants for ligand binding and catalysis of triosephosphate isomerase.

Eur. J. Biochem. 268(19) , 5189-96, (2001)

The crystal structure of leishmania triosephosphate isomerase (TIM) complexed with 2-(N-formyl-N-hydroxy)-aminoethyl phosphonate (IPP) highlights the importance of Asn11 for binding and catalysis. IPP...

Synthesis of rhodamines from fluoresceins using Pd-catalyzed C-N cross-coupling. Grimm JB and Lavis LD.

Org. Lett. 13(24) , 6354-6357, (2011)

 Synonyms

tert-butyl benzyloxycarbamate
Carbamic acid, N-(phenylmethoxy)-, 1,1-dimethylethyl ester
tert-Butyl (benzyloxy)carbamate
2-Methyl-2-propanyl (benzyloxy)carbamate
tert-butyl N-phenylmethoxycarbamate
MFCD00191873