Tetrabromobisphenol A

Modify Date: 2024-01-02 17:23:35

Tetrabromobisphenol A Structure
Tetrabromobisphenol A structure
Common Name Tetrabromobisphenol A
CAS Number 79-94-7 Molecular Weight 543.871
Density 2.1±0.1 g/cm3 Boiling Point 417.9±40.0 °C at 760 mmHg
Molecular Formula C15H12Br4O2 Melting Point 178-181 °C(lit.)
MSDS Chinese USA Flash Point 206.6±27.3 °C
Symbol GHS09
GHS09
Signal Word Warning

 Names

Name 3,3',5,5'-tetrabromobisphenol A
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.1±0.1 g/cm3
Boiling Point 417.9±40.0 °C at 760 mmHg
Melting Point 178-181 °C(lit.)
Molecular Formula C15H12Br4O2
Molecular Weight 543.871
Flash Point 206.6±27.3 °C
Exact Mass 539.757080
PSA 40.46000
LogP 7.29
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.672
Water Solubility Insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SM0894500
CHEMICAL NAME :
Phenol, 4,4'-(1-methylethylidene)bis(2,6-dibromo-
CAS REGISTRY NUMBER :
79-94-7
LAST UPDATED :
199712
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C15-H12-Br4-O2
MOLECULAR WEIGHT :
543.91

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>10920 mg/m3/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>500 mg/m3/8H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>3160 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
>500 mg/m3/8H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
100 gm/kg/4W-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - other changes in urine composition Endocrine - hyperglycemia Related to Chronic Data - death
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525426

 Safety Information

Symbol GHS09
GHS09
Signal Word Warning
Hazard Statements H410
Precautionary Statements P273-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant
Risk Phrases R36/37/38
Safety Phrases S26-S36-S37/39
RIDADR UN 3077 9/PG 3
WGK Germany 1
RTECS SM0894500
Packaging Group II
Hazard Class 9
HS Code 2908199090

 Synthetic Route

~98%

Tetrabromobisphenol A Structure

Tetrabromobisph...

CAS#:79-94-7

Literature: Kumar, Lalit; Sharma, Vivek; Mahajan, Tanu; Agarwal Organic Process Research and Development, 2010 , vol. 14, # 1 p. 174 - 179

 Customs

HS Code 2908199090
Summary HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

 Articles67

More Articles
Photochemical transformation of tetrabromobisphenol A under simulated sunlight irradiation: Kinetics, mechanism and influencing factors.

Chemosphere 134 , 550-6, (2015)

A systematic study on photolysis of tetrabromobisphenol A (2,2',6,6'-tetrabromo-4,4'-isopropylidendiphenol, TBBPA) in water was investigated under simulated sunlight irradiation. The results showed th...

Analytical capabilities of high performance liquid chromatography - Atmospheric pressure photoionization - Orbitrap mass spectrometry (HPLC-APPI-Orbitrap-MS) for the trace determination of novel and emerging flame retardants in fish.

Anal. Chim. Acta 898 , 60-72, (2015)

A new analytical method was established and validated for the analysis of 27 brominated flame retardants (BFRs), including so called "emerging" and "novel" BFRs (EBFRs and NBFRs) in fish samples. High...

Flame retardant emission from e-waste recycling operation in northern Vietnam: environmental occurrence of emerging organophosphorus esters used as alternatives for PBDEs.

Sci. Total Environ. 514 , 492-9, (2015)

Three oligomeric organophosphorus flame retardants (o-PFRs), eight monomeric PFRs (m-PFRs), tetrabromobisphenol A (TBBPA), and polybrominated diphenyl ethers (PBDEs) were identified and quantified in ...

 Synonyms

3,3',5,5'-Tetrabromobisphenol A
2,2',6,6'-tetrabromo-4,4'-propane-2,2-diyldiphenol
tetrabromobisphenol-A
MFCD00013962
TBBA
4,4'-Isopropylidenebis(2,6-dibromophenol)
FG 2000
Bromdian
ba59
SAYTEX RB-100
4,4'-(2,2-Propanediyl)bis(2,6-dibromophenol)
EINECS 201-236-9
4,4'-Propan-2,2-diylbis(2,6-dibromphenol)
FR-1524
Tetrabromobisphenol A
4,4'-propane-2,2-diylbis(2,6-dibromophenol)
3,3',5,5'-tetrabromo bisphenol a
saytexrb100pc
Phenol, 4,4'-(1-methylethylidene)bis[2,6-dibromo-
2,6-dibromo-4-[1-(3,5-dibromo-4-hydroxyphenyl)-1-methylethyl]phenol
fireguard2000
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