2-Methyl-2-propanyl (2-bromophenyl)carbamate

Modify Date: 2025-08-25 11:00:49

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure
2-Methyl-2-propanyl (2-bromophenyl)carbamate structure
Common Name 2-Methyl-2-propanyl (2-bromophenyl)carbamate
CAS Number 78839-75-5 Molecular Weight 272.138
Density 1.4±0.1 g/cm3 Boiling Point 279.2±23.0 °C at 760 mmHg
Molecular Formula C11H14BrNO2 Melting Point N/A
MSDS USA Flash Point 122.6±22.6 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name tert-butyl N-(2-bromophenyl)carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 279.2±23.0 °C at 760 mmHg
Molecular Formula C11H14BrNO2
Molecular Weight 272.138
Flash Point 122.6±22.6 °C
Exact Mass 271.020782
PSA 38.33000
LogP 3.48
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.570

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2924299090

 Synthetic Route

~95%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Colobert, Francoise; Valdivia, Victoria; Choppin, Sabine; Leroux, Frederic R.; Fernandez, Inmaculada; Alvarez, Eleuterio; Khiar, Noureddine Organic Letters, 2009 , vol. 11, # 22 p. 5130 - 5133

~79%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Bellezza, Francesca; Cipiciani, Antonio; Ruzziconi, Renzo; Spizzichino, Sara Journal of Fluorine Chemistry, 2008 , vol. 129, # 2 p. 97 - 107

~76%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Poriel, Cyril; Metivier, Remi; Rault-Berthelot, Joelle; Thirion, Damien; Barriere, Frederic; Jeannin, Olivier Chemical Communications, 2011 , vol. 47, # 42 p. 11703 - 11705

~%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Journal of the American Chemical Society, , vol. 116, # 26 p. 11723 - 11736

~%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Kessler, Albane; Coleman, Claire M.; Charoenying, Patchanee; O'Shea, Donal F. Journal of Organic Chemistry, 2004 , vol. 69, # 23 p. 7836 - 7846

~%

2-Methyl-2-propanyl (2-bromophenyl)carbamate Structure

2-Methyl-2-prop...

CAS#:78839-75-5

Literature: Journal of Organic Chemistry, , vol. 69, # 23 p. 7836 - 7846

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles2

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Development of a Brønsted acid-promoted arene-ynamide cyclization toward the total syntheses of marinoquinolines A and C and aplidiopsamine A.

J. Org. Chem. 80(2) , 957-64, (2015)

A Brønsted acid-promoted arene-ynamide cyclization has been developed to construct the 3H-pyrrolo[2,3-c]quinolines. This reaction consists of the generation of a highly reactive keteniminium intermedi...

Novel reduction of perfluoroalkyl ketones with lithium alkoxides. Sokeirik YS, et al.

J. Fluor. Chem. 127(1) , 150-152, (2006)

 Synonyms

(2-Bromophenyl)carbamic acid,1,1-dimethylethyl ester
(2-bromophenyl)carbamic acid tert-butyl ester
MFCD01006614
N-(tert-Butoxycarbonyl)-2-bromoaniline
tert-Butyl (2-bromophenyl)carbamate
Carbamic acid, N-(2-bromophenyl)-, 1,1-dimethylethyl ester
N-(2-bromophenyl)carbamic acid tert-butyl ester
N-Boc 2-bromoaniline
2-Bromo-N-(tert-butoxycarbonyl) aniline
(2-bromophenyl)carbamic acid t-butyl ester
2-Methyl-2-propanyl (2-bromophenyl)carbamate
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