2-Methyl-2-propanyl (2-bromophenyl)carbamate

Names

[ Name ]:
2-Methyl-2-propanyl (2-bromophenyl)carbamate

[Synonym ]:
(2-Bromophenyl)carbamic acid,1,1-dimethylethyl ester
(2-bromophenyl)carbamic acid tert-butyl ester
MFCD01006614
N-(tert-Butoxycarbonyl)-2-bromoaniline
tert-Butyl (2-bromophenyl)carbamate
Carbamic acid, N-(2-bromophenyl)-, 1,1-dimethylethyl ester
N-(2-bromophenyl)carbamic acid tert-butyl ester
N-Boc 2-bromoaniline
2-Bromo-N-(tert-butoxycarbonyl) aniline
(2-bromophenyl)carbamic acid t-butyl ester
2-Methyl-2-propanyl (2-bromophenyl)carbamate

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
279.2±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₁H₁₄BrNO₂

[ Molecular Weight ]:
272.138

[ Flash Point ]:
122.6±22.6 °C

[ Exact Mass ]:
271.020782

[ PSA ]:
38.33000

[ LogP ]:
3.48

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.570

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Development of a Brønsted acid-promoted arene-ynamide cyclization toward the total syntheses of marinoquinolines A and C and aplidiopsamine A.

J. Org. Chem. 80(2) , 957-64, (2015)

A Brønsted acid-promoted arene-ynamide cyclization has been developed to construct the 3H-pyrrolo[2,3-c]quinolines. This reaction consists of the generation of a highly reactive keteniminium intermedi...

Novel reduction of perfluoroalkyl ketones with lithium alkoxides. Sokeirik YS, et al.

J. Fluor. Chem. 127(1) , 150-152, (2006)