4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate

Modify Date: 2024-01-22 15:42:00

4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate Structure
4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate structure
Common Name 4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate
CAS Number 67229-93-0 Molecular Weight 266.31800
Density 1.27g/cm3 Boiling Point 419.1ºC at 760 mmHg
Molecular Formula C15H10N2OS Melting Point 140-150ºC (dec.)
MSDS USA Flash Point 207.3ºC

 Names

Name 4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.27g/cm3
Boiling Point 419.1ºC at 760 mmHg
Melting Point 140-150ºC (dec.)
Molecular Formula C15H10N2OS
Molecular Weight 266.31800
Flash Point 207.3ºC
Exact Mass 266.05100
PSA 70.56000
LogP 4.23900
Index of Refraction 1.676
Storage condition 2-8°C

 MSDS

Version 1.4
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product Name4-(6-METHYL-2-BENZOTHIAZOLYL)PHENYL
ISOCYANATE SUITABLE FOR FLUORESCENCE,
PURUM, FOR FLUORESCENCE, >= 98.0% (HPLC)

2 - Hazards Identification

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
4-(6-METHYL-2-BENZOTHIAZOLYL)PHENY 67229-93-0 NoneNone
L ISOCYANATE
FormulaC15H10N2OS
Molecular Weight 266,3000 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
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Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place.
Store at 2-8°C

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.

9 - Physical and Chemical Properties

AppearanceColor: Faintly beige
Form: Fine crystals
PropertyValueAt Temperature or Pressure
pHN/A
BP/BP RangeN/A
MP/MP Range140,000 °C
Flash PointN/A
FlammabilityN/A
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Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Sulfur oxides, Hydrogen cyanide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SENSITIZATION
Sensitization: Prolonged or repeated exposure may cause allergic
reactions in certain sensitive individuals.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: Causes eye and skin irritation. Harmful if
swallowed, inhaled, or absorbed through skin.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Dissolve or mix the material with a combustible solvent and burn
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in a chemical incinerator equipped with an afterburner and
scrubber. Observe all federal, state, and local environmental
regulations.

14 - Transport Information

RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
S-PHRASES: 22-24/25
Do not breathe dust. Avoid contact with skin and eyes.
Caution: Substance not yet fully tested (EU).
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 3
Self-Classification

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
SIGMAwww.molbase.com


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Safety Phrases 22-24/25
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2934200090

 Synthetic Route

~%

4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate Structure

4-(6-Methyl-2-b...

CAS#:67229-93-0

Literature: Biedermann, Frank; Appel, Eric A.; Del Barrio, Jesus; Gruendling, Till; Barner-Kowollik, Christopher; Scherman, Oren A. Macromolecules, 2011 , vol. 44, # 12 p. 4828 - 4835

~%

4-(6-Methyl-2-benzothiazolyl)phenyl isocyanate Structure

4-(6-Methyl-2-b...

CAS#:67229-93-0

Literature: Weisswange,W. Diss. 49 Full Text Show Details Siefken Justus Liebigs Annalen der Chemie, 1949 , vol. 562, p. 75,1114

 Precursor & DownStream

Precursor  3

DownStream  0

 Customs

HS Code 2934200090
Summary 2934200090. other compounds containing in the structure a benzothiazole ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles2

More Articles
R. Wintersteiger et al.

Fresenius J. Anal. Chem. 312 , 455, (1982)

O.S. Wolfbeis, H. Marhold

Monatsh. Chem 114 , 599, (1983)

 Synonyms

2-(4-isocyanatophenyl)-6-methyl-1,3-benzothiazole
MFCD00467423