[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane

Modify Date: 2024-01-02 20:33:36

[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure
[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane structure
Common Name [(1E)-1,3-Butadien-1-yloxy](trimethyl)silane
CAS Number 6651-43-0 Molecular Weight 142.271
Density 0.8±0.1 g/cm3 Boiling Point 135.7±8.0 °C at 760 mmHg
Molecular Formula C7H14OSi Melting Point N/A
MSDS Chinese USA Flash Point 25.0±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name buta-1,3-dienoxy(trimethyl)silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.8±0.1 g/cm3
Boiling Point 135.7±8.0 °C at 760 mmHg
Molecular Formula C7H14OSi
Molecular Weight 142.271
Flash Point 25.0±0.0 °C
Exact Mass 142.081390
PSA 9.23000
LogP 2.76
Vapour Pressure 9.4±0.2 mmHg at 25°C
Index of Refraction 1.425
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases 10-36/37/38
Safety Phrases S26-S36-S37-S39
RIDADR UN 1993 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~65%

[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure

[(1E)-1,3-Butad...

CAS#:6651-43-0

Literature: Jung, Michael E.; Gardiner, John M. Journal of Organic Chemistry, 1991 , vol. 56, # 8 p. 2614 - 2615 Title/Abstract Full Text View citing articles Show Details Jung, Michael E.; Castro, Claire; Gardiner, John M. Tetrahedron Letters, 1991 , vol. 32, # 41 p. 5717 - 5720

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[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure

[(1E)-1,3-Butad...

CAS#:6651-43-0

Literature: Tetrahedron Letters, , vol. 36, # 10 p. 1641 - 1644

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[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure

[(1E)-1,3-Butad...

CAS#:6651-43-0

Literature: Tetrahedron, , vol. 52, # 21 p. 7487 - 7510

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[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure

[(1E)-1,3-Butad...

CAS#:6651-43-0

Literature: Journal of Organic Chemistry USSR (English Translation), , p. 1001 - 1003 Zhurnal Organicheskoi Khimii, , vol. 18, # 6 p. 1159 - 1162

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[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane Structure

[(1E)-1,3-Butad...

CAS#:6651-43-0

Literature: Tetrahedron Letters, , vol. 22, # 29 p. 2833 - 2836

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
Mechanistic insights into the stepwise Diels-Alder reaction of 4,6-dinitrobenzofuroxan.

Org. Lett. 14(1) , 118-21, (2012)

The stepwise Diels-Alder reaction between 1-trimethylsiloxy-1,3-butadiene and 4,6-dinitrobenzofuroxan is explored using state-of-the-art computational methods. The results support a stepwise mechanism...

 Synonyms

Silane,(1,3-butadienyloxy)trimethyl
Silane, [(1E)-1,3-butadien-1-yloxy]trimethyl-
(E/Z)-1-[(trimethylsilyl)-oxy]buta-1,3-diene
MFCD00009647
1-trimethylsilyloxybuta-1,3-diene
[(1E)-Buta-1,3-dien-1-yloxy](trimethyl)silane
[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane
1-(trimethylsiloxy)-1,3-butadiene
1-(trimethylsilyloxy)-1,3-butadiene