[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane
Names
[ CAS No. ]:
6651-43-0
[ Name ]:
[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane
[Synonym ]:
Silane,(1,3-butadienyloxy)trimethyl
Silane, [(1E)-1,3-butadien-1-yloxy]trimethyl-
(E/Z)-1-[(trimethylsilyl)-oxy]buta-1,3-diene
MFCD00009647
1-trimethylsilyloxybuta-1,3-diene
[(1E)-Buta-1,3-dien-1-yloxy](trimethyl)silane
[(1E)-1,3-Butadien-1-yloxy](trimethyl)silane
1-(trimethylsiloxy)-1,3-butadiene
1-(trimethylsilyloxy)-1,3-butadiene
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
135.7±8.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H14OSi
[ Molecular Weight ]:
142.271
[ Flash Point ]:
25.0±0.0 °C
[ Exact Mass ]:
142.081390
[ PSA ]:
9.23000
[ LogP ]:
2.76
[ Vapour Pressure ]:
9.4±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.425
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
10-36/37/38
[ Safety Phrases ]:
S26-S36-S37-S39
[ RIDADR ]:
UN 1993 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
[ HS Code ]:
2931900090
Synthetic Route
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Lett. 14(1) , 118-21, (2012)
The stepwise Diels-Alder reaction between 1-trimethylsiloxy-1,3-butadiene and 4,6-dinitrobenzofuroxan is explored using state-of-the-art computational methods. The results support a stepwise mechanism...