(S)-(+)-Methoprene

Modify Date: 2024-01-08 04:35:59

(S)-(+)-Methoprene Structure
(S)-(+)-Methoprene structure
Common Name (S)-(+)-Methoprene
CAS Number 65733-16-6 Molecular Weight 310.471
Density 0.9±0.1 g/cm3 Boiling Point 385.7±25.0 °C at 760 mmHg
Molecular Formula C19H34O3 Melting Point N/A
MSDS N/A Flash Point 162.4±17.8 °C

 Use of (S)-(+)-Methoprene


(S)-Methoprene is a juvenile hormone analogue that prohibits the ability of the insect to change from pupae to adult and is used as an insecticide[1].

 Names

Name s-(+)-methoprene
Synonym More Synonyms

 (S)-(+)-Methoprene Biological Activity

Description (S)-Methoprene is a juvenile hormone analogue that prohibits the ability of the insect to change from pupae to adult and is used as an insecticide[1].
Related Catalog
References

[1]. Adnan SM, et al. Accelerated Sexual Maturation in Methoprene-Treated Sterile and Fertile Male Queensland Fruit Flies (Diptera: Tephritidae), and Mosquito Larvicide as an Economical and Effective Source of Methoprene. J Econ Entomol. 2019 Dec 9;112(6):2842-2849.

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 385.7±25.0 °C at 760 mmHg
Molecular Formula C19H34O3
Molecular Weight 310.471
Flash Point 162.4±17.8 °C
Exact Mass 310.250793
PSA 35.53000
LogP 5.63
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.462

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: S-(+)-Methoprene
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:S-(+)-Methoprene
CAS number:65733-16-6

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels, refrigerated.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C19H34O3
Molecular weight:310.5

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi

 Synthetic Route

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(S)-(+)-Methoprene Structure

(S)-(+)-Methoprene

CAS#:65733-16-6

Literature: Russian Journal of Organic Chemistry, , vol. 33, # 4 p. 467 - 474

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Detail
Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 40, # 4.1 p. 739 - 743 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 842 - 846

~%

(S)-(+)-Methoprene Structure

(S)-(+)-Methoprene

CAS#:65733-16-6

Literature: Russian Journal of Organic Chemistry, , vol. 33, # 4 p. 467 - 474

~%

(S)-(+)-Methoprene Structure

(S)-(+)-Methoprene

CAS#:65733-16-6

Literature: Russian Journal of Organic Chemistry, , vol. 33, # 4 p. 467 - 474

~%

(S)-(+)-Methoprene Structure

(S)-(+)-Methoprene

CAS#:65733-16-6

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 40, # 4.1 p. 739 - 743 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 842 - 846

~%

(S)-(+)-Methoprene Structure

(S)-(+)-Methoprene

CAS#:65733-16-6

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 40, # 4.1 p. 739 - 743 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 842 - 846

 Synonyms

METHOPRENE, (S)-
Isopropyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyldodeca-2,4-dienoate
(2E,4E,7S)-1-Methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate
S-METHOPRENE
Flea killer plus
Methoprene
(2E,4E,7S)-11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid isopropyl ester
7S-Methoprene
isopropyl-S-(2E,4E)-11-methoxy-3,7,11-trimethyl-dodecadienoate
2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, 1-methylethyl ester, (2E,4E,7S)-
Isopropyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate
(S)-methoprene
1-Methylethyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate
S-(+)-11-methoxy-3,7,11-trimethyl-2E,4E-dodecadienoic acid isopropyl ester
D-Methoprene
Isopropyl (2E,4E)-(7S)-11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate
isopropyl (E,E)-(7S)-11-methoxy-3,7,11-trimethyldodeca-2,4-dienoate