1-(2-Fluorophenyl)thiourea

Modify Date: 2025-08-25 14:17:06

1-(2-Fluorophenyl)thiourea Structure
1-(2-Fluorophenyl)thiourea structure
Common Name 1-(2-Fluorophenyl)thiourea
CAS Number 656-32-6 Molecular Weight 170.207
Density 1.4±0.1 g/cm3 Boiling Point 257.0±42.0 °C at 760 mmHg
Molecular Formula C7H7FN2S Melting Point 143-145°C
MSDS N/A Flash Point 109.2±27.9 °C

 Names

Name 1-(2-Fluorophenyl)-2-Thiourea
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 257.0±42.0 °C at 760 mmHg
Melting Point 143-145°C
Molecular Formula C7H7FN2S
Molecular Weight 170.207
Flash Point 109.2±27.9 °C
Exact Mass 170.031403
PSA 70.14000
LogP 0.69
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.693
InChIKey WYVZQQOFMQRNPF-UHFFFAOYSA-N
SMILES NC(=S)Nc1ccccc1F

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: (2-Fluorophenyl)thiourea
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H301:Toxic if swallowed
P309:IF exposed or you feel unwell:
P310:Immediately call a POISON CENTER or doctor/physician

Section3. Composition/information on ingredients.
Ingredient name:(2-Fluorophenyl)thiourea
CAS number:656-32-6

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula:C7H7FN2S
Molecular weight:170.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen fluoride, sulfur oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN2811 Class: 6.1 Packing group: III
Proper shipping name: TOXIC SOLIDS, ORGANIC, N.O.S. ((2-Fluorophenyl)thiourea)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes T
Risk Phrases R25
Safety Phrases S22-S36/37/39
RIDADR 2811
HS Code 2930909090

 Synthetic Route

~%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 11, # 7 p. 915 - 918

~86%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Gupta, K. A.; Saxena, Anil K.; Jain, Padam C. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1982 , vol. 21, # 3 p. 228 - 233

~88%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Gupta, R. R.; Kumar, Rakesh Synthetic Communications, 1987 , vol. 17, # 2 p. 229 - 240

~%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 11, # 7 p. 915 - 918

~%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 21, # 3 p. 228 - 233

~%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 20, # 3 p. 1177 - 1180

~%

1-(2-Fluorophenyl)thiourea Structure

1-(2-Fluorophen...

CAS#:656-32-6

Literature: Journal of the Chemical Society [Section] C: Organic, , p. 268 - 272

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

Thiourea, N-(2-fluorophenyl)-
1-(2-Fluorophenyl)thiourea
(2-fluorophenyl)thiourea
MFCD00041148
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