3-Chloro-2-methyl-1-propene

Modify Date: 2025-08-25 13:29:19

3-Chloro-2-methyl-1-propene Structure
3-Chloro-2-methyl-1-propene structure
 Common Name 3-Chloro-2-methyl-1-propene
CAS Number 563-47-3 Molecular Weight 90.551
Density 0.9±0.1 g/cm3 Boiling Point 72.4±9.0 °C at 760 mmHg
Molecular Formula C4H7Cl Melting Point -80 °C
MSDS Chinese USA Flash Point -10.0±0.0 °C
Symbol GHS02 GHS05 GHS07 GHS09
GHS02, GHS05, GHS07, GHS09		 Signal Word Danger

 Names

Name 3-Chloro-2-methylpropene
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 72.4±9.0 °C at 760 mmHg
Melting Point -80 °C
Molecular Formula C4H7Cl
Molecular Weight 90.551
Flash Point -10.0±0.0 °C
Exact Mass 90.023628
LogP 2.20
Vapour density 3.12 (vs air)
Vapour Pressure 129.6±0.1 mmHg at 25°C
Index of Refraction 1.410
Water Solubility 0.5 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UC8050000
CHEMICAL NAME :
Propene, 3-chloro-2-methyl-
CAS REGISTRY NUMBER :
563-47-3
BEILSTEIN REFERENCE NO. :
0878160
LAST UPDATED :
199801
DATA ITEMS CITED :
30
MOLECULAR FORMULA :
C4-H7-Cl
MOLECULAR WEIGHT :
90.56
WISWESSER LINE NOTATION :
G1Y1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
22000 ppm/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
848 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Gastrointestinal - hypermotility, diarrhea Blood - hemorrhage
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
34 gm/m3/30M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3160 mg/kg
TOXIC EFFECTS :
Gastrointestinal - other changes Liver - other changes Blood - changes in spleen
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7 gm/kg/14D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
19500 mg/kg/13W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
16 gm/m3/1H/5W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10500 mg/kg/14D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
81250 mg/kg/13W-I
TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
77250 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Endocrine - adrenal cortex tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
38625 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
51500 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
51500 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
77250 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Gastrointestinal - tumors Reproductive - Tumorigenic effects - testicular tumors
TYPE OF TEST :
Sex chromosome loss and nondisjunction

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
16 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 13,133,1989 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83971 No. of Facilities: 33 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1683 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS09
GHS02, GHS05, GHS07, GHS09
Signal Word Danger
Hazard Statements H225-H302 + H332-H314-H317-H411
Precautionary Statements P210-P273-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
Risk Phrases R11;R20/22;R34;R43;R51/53
Safety Phrases S9-S16-S29-S36/37/39-S45-S61-S26
RIDADR UN 2554 3/PG 2
WGK Germany 2
RTECS UC8050000
Packaging Group II
Hazard Class 3
HS Code 2903299090

 Synthetic Route

 Customs

HS Code 2903299090
Summary 2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Articles16

More Articles
NTP Toxicology and Carcinogenesis Studies of 3-Chloro-2-methylpropene (Technical grade containing 5% dimethylvinyl chloride) (CAS No. 563-47-3) in F344/N Rats and B6C3F1 Mice (Gavage Studies).

Natl. Toxicol. Program Tech. Rep. Ser. 300 , 1-196, (1986)

Toxicology and carcinogenesis studies of technical-grade 3-chloro-2-methylpropene (containing 5% dimethylvinyl chloride), a widely used insecticide and a chemical intermediate, were performed on F344/...

3-Chloro-2-methylpropene.

IARC Monogr. Eval. Carcinog. Risks Hum. 63 , 325-33, (1995)

3-Chloro-2-methylpropene.

Rep. Carcinog. 12 , 100-1, (2011)

 Synonyms

MFCD00000953
1-Propene, 3-chloro-2-methyl-
EINECS 209-251-2
3-Chloro-2-methyl-1-propene
3-Chloro-2-methylprop-1-ene
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Chemsrc provides 3-Chloro-2-methyl-1-propene(CAS#:563-47-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of 3-Chloro-2-methyl-1-propene are included as well.>> amp version: 3-Chloro-2-methyl-1-propene

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