Titanium(4+) tetrapropan-2-olate

Modify Date: 2024-01-02 18:23:29

Titanium(4+) tetrapropan-2-olate Structure
Titanium(4+) tetrapropan-2-olate structure
 Common Name Titanium(4+) tetrapropan-2-olate
CAS Number 546-68-9 Molecular Weight 284.215
Density 0.96 g/mL at 20 °C(lit.) Boiling Point 232 °C(lit.)
Molecular Formula C12H28O4Ti Melting Point 14-17 °C(lit.)
MSDS Chinese USA Flash Point 72 °F
Symbol GHS02 GHS07
GHS02, GHS07		 Signal Word Warning

 Names

Name Titanium tetraisopropanolate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.96 g/mL at 20 °C(lit.)
Boiling Point 232 °C(lit.)
Melting Point 14-17 °C(lit.)
Molecular Formula C12H28O4Ti
Molecular Weight 284.215
Flash Point 72 °F
Exact Mass 284.146698
PSA 36.92000
LogP 3.50280
Index of Refraction n20/D 1.464(lit.)
Storage condition Flammables area
Stability Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
Water Solubility HYDROLYSIS
Freezing Point 14.8℃

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NT8060000
CHEMICAL NAME :
Isopropyl alcohol, titanium(4+) salt
CAS REGISTRY NUMBER :
546-68-9
LAST UPDATED :
199701
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C3-H8-O.1/4Ti
MOLECULAR WEIGHT :
72.07
WISWESSER LINE NOTATION :
3O-TI-O3&O3&O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7460 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>16 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83587 No. of Facilities: 150 (estimated) No. of Industries: 8 No. of Occupations: 30 No. of Employees: 9667 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83587 No. of Facilities: 601 (estimated) No. of Industries: 15 No. of Occupations: 26 No. of Employees: 13193 (estimated) No. of Female Employees: 2925 (estimated)

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H319-H336
Precautionary Statements P280-P305 + P351 + P338-P337 + P313-P403 + P235
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R10;R36
Safety Phrases S16-S26-S36/37/39
RIDADR UN 2413 3/PG 3
WGK Germany 2
RTECS NT8060000
Packaging Group III
Hazard Class 3
HS Code 29051900

 Synthetic Route

Titanium tetrachloride structure

Titanium tetrac...

CAS#:7550-45-0
Isopropanol structure

Isopropanol

CAS#:67-63-0

~71%

Titanium(4+) tetrapropan-2-olate Structure

Titanium(4+) te...

CAS#:546-68-9
Literature: Rani, I.; Pandeya, K. B.; Singh, R. P. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 221 - 230
Sodium isopropoxide structure

Sodium isopropoxide

CAS#:683-60-3
Titanium tetrachloride structure

Titanium tetrac...

CAS#:7550-45-0

~61%

Titanium(4+) tetrapropan-2-olate Structure

Titanium(4+) te...

CAS#:546-68-9
Literature: Tomashpol'skii; Golikova; Rybakova Inorganic Materials, 2002 , vol. 38, # 9 p. 945 - 948
titanium structure

titanium

CAS#:7440-32-6
Isopropanol structure

Isopropanol

CAS#:67-63-0

~%

Titanium(4+) tetrapropan-2-olate Structure

Titanium(4+) te...

CAS#:546-68-9
Literature: Inorganica Chimica Acta, , vol. 53, p. L73 - L76
diisopropoxy-bis(N,N-diethylamine-N-carbodithioato)titanium(IV) structure

diisopropoxy-bi...

CAS#:66752-45-2

~%

Titanium(4+) tetrapropan-2-olate Structure

Titanium(4+) te...

CAS#:546-68-9

isopropoxy-tris(N'-methylpiperidine-N-carbodithioato)titanium(IV) structure

isopropoxy-tris...

CAS#:1148038-63-4
Literature: Inorganic Chemistry, , vol. 48, # 9 p. 4171 - 4178
2-(METHYLSULFINYL)ETHANAMINE HYDROCHLORIDE structure

2-(METHYLSULFIN...

CAS#:18006-13-8
ch3cho structure

ch3cho

CAS#:75-07-0

~%

Titanium(4+) tetrapropan-2-olate Structure

Titanium(4+) te...

CAS#:546-68-9
Literature: Inorganica Chimica Acta, , vol. 52, p. 79 - 82

 Customs

HS Code 29051900

 Articles71

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 Synonyms

Titanium(IV) Isopropoxide
Titanium(4+) tetra(2-propanolate)
TITANIUM ISOPROPOXIDE
titanium(4+)salt
EINECS 208-909-6
Titanium(IV) isoprop
VERTEC(TM) TIPT
Titaniumispropoxide
titanium(IV) isopropylate
2-Propanol, titanium(4+) salt (4:1)
Ti(OCH(CH3)2)4
tyzortpt
MFCD00008871
Titanium(4+) tetrapropan-2-olate
TITANIUM ISO-PROPYLATE
tiisopropylate
ISOPROPYL TITANATE
Iso-propy titanate
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