N-Glycidylphthalimide

Modify Date: 2024-01-03 11:09:59

N-Glycidylphthalimide Structure
N-Glycidylphthalimide structure
 Common Name N-Glycidylphthalimide
CAS Number 5455-98-1 Molecular Weight 203.194
Density 1.4±0.1 g/cm3 Boiling Point 347.4±15.0 °C at 760 mmHg
Molecular Formula C11H9NO3 Melting Point 92-98 °C(lit.)
MSDS Chinese USA Flash Point 163.9±20.4 °C
Symbol GHS05
GHS05		 Signal Word Danger

 Names

Name N-Glycidyl Phthalimide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 347.4±15.0 °C at 760 mmHg
Melting Point 92-98 °C(lit.)
Molecular Formula C11H9NO3
Molecular Weight 203.194
Flash Point 163.9±20.4 °C
Exact Mass 203.058243
PSA 49.91000
LogP 1.60
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.649

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TI4950000
CHEMICAL NAME :
Phthalimide, N-(2,3-epoxypropyl)-
CAS REGISTRY NUMBER :
5455-98-1
BEILSTEIN REFERENCE NO. :
0171277
LAST UPDATED :
199712
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C11-H9-N-O3
MOLECULAR WEIGHT :
203.21
WISWESSER LINE NOTATION :
T56 BVNVJ C1- BT3OTJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4700 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia Gastrointestinal - changes in structure or function of salivary glands
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4400 mg/m3/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes

MUTATION DATA

TYPE OF TEST :
Mutation in mammalian somatic cells
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
10 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 68,251,1979

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H318
Precautionary Statements P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R41
Safety Phrases S26-S39
RIDADR NONH for all modes of transport
WGK Germany 2
RTECS TI4950000
HS Code 2925190090

 Synthetic Route

Potassium phthalimide structure

Potassium phtha...

CAS#:1074-82-4
Epibromohydrin structure

Epibromohydrin

CAS#:3132-64-7

~51%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Kirin Beer Kabushiki Kaisha Patent: US6875884 B1, 2005 ; Location in patent: Page/Page column 26; 203-204 ; US 6875884 B1
Potassium phthalimide structure

Potassium phtha...

CAS#:1074-82-4
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~92%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Meyer, Joerg; Keul, Helmut; Moeller, Martin Macromolecules, 2011 , vol. 44, # 11 p. 4082 - 4091
1H-Isoindole-1,3(2H)-dione,2-(2-propen-1-yl)- structure

1H-Isoindole-1,...

CAS#:5428-09-1

~99%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Carruthers, Nicholas I.; Spitler, James M.; Wong, Shing-Chun; Blythin, David J.; Chen, Xiao; Shue, Ho-Jane; She, Hoyan S.; Lee, Joe F.; Rizzo, Charles; Ting, Pauline C.; West Jr., Robert E. Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 21 p. 3059 - 3064
phthalimide structure

phthalimide

CAS#:136918-14-4
Glycidol structure

Glycidol

CAS#:556-52-5

~77%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Ishige, Hirohide; Ishiyama, Nobuo; Mimura, Mitsuo; Hayashida, Mitsuo; Okuno, Tadashi; Ukai, Kiyoharu; Kiyofuji, Takeshi; Yoneda, Yasuo; Tauchi, Shinji; Aoyama, Akinori; Inoguchi, Kiyoshi Heterocycles, 2006 , vol. 67, # 2 p. 561 - 566
1H-Isoindole-1,3(2H)-dione,2-(3-chloro-2-hydroxypropyl)- structure

1H-Isoindole-1,...

CAS#:19667-37-9

~98%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Pace, Vittorio; Hoyos, Pilar; Sinisterra, Jose Vicente; Alcantara, Andres R.; Holzer, Wolfgang Synlett, 2011 , # 13 p. 1831 - 1834
phthalimide structure

phthalimide

CAS#:136918-14-4
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~89%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Hu, Yi; Chen, Zhen-Chu; Le, Zhang-Gao; Zheng, Qin-Guo Journal of Chemical Research, 2004 , # 4 p. 276 - 278
phthalimide structure

phthalimide

CAS#:136918-14-4
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~11%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1

1H-Isoindole-1,3(2H)-dione,2-(3-chloro-2-hydroxypropyl)- structure

1H-Isoindole-1,...

CAS#:19667-37-9
Literature: Green Chemistry, , vol. 12, # 8 p. 1380 - 1382
Potassium phthalimide structure

Potassium phtha...

CAS#:1074-82-4

~%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: Journal of Medicinal Chemistry, , vol. 45, # 1 p. 99 - 114
oxiran-2-ylmethyl 4-methyl-1-benzenesulfonate structure

oxiran-2-ylmeth...

CAS#:118712-54-2

~%

N-Glycidylphthalimide Structure

N-Glycidylphtha...

CAS#:5455-98-1
Literature: US5663173 A1, ; US 5663173 A

 Customs

HS Code 2925190090
Summary 2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

N-Glycidylphthalimide
1H-Isoindole-1,3(2H)-dione, 2-(oxiranylmethyl)-
EINECS 226-710-2
2-(oxiran-2-ylmethyl)-1H-isoindole-1,3(2H)-dione
n-(2,3-epoxypropyl)phthalimide
2-(2-Oxiranylmethyl)-1H-isoindole-1,3(2H)-dione
N-Glycidyl phthalimide
MFCD00005896
N-(2,3-Epoxypropyl)-o-Phthalimide
2-((OXIRAN-2-YL)METHYL)ISOINDOLINE-1,3-DIONE
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