N,N-DIMETHYL-4,4'-AZODIANILINE

Modify Date: 2024-01-03 23:00:08

N,N-DIMETHYL-4,4'-AZODIANILINE Structure
N,N-DIMETHYL-4,4'-AZODIANILINE structure
Common Name N,N-DIMETHYL-4,4'-AZODIANILINE
CAS Number 539-17-3 Molecular Weight 240.30400
Density 1.11g/cm3 Boiling Point 431.1ºC at 760mmHg
Molecular Formula C14H16N4 Melting Point 190-195 °C (dec.)
MSDS Chinese USA Flash Point 214.5ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name n,n-dimethyl-4,4'-azodianiline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.11g/cm3
Boiling Point 431.1ºC at 760mmHg
Melting Point 190-195 °C (dec.)
Molecular Formula C14H16N4
Molecular Weight 240.30400
Flash Point 214.5ºC
Exact Mass 240.13700
PSA 53.98000
LogP 4.33140
Index of Refraction 1.595
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX5020000
CHEMICAL NAME :
Aniline, 4-(p-dimethylaminophenylazo)-
CAS REGISTRY NUMBER :
539-17-3
BEILSTEIN REFERENCE NO. :
0748253
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C14-H16-N4
MOLECULAR WEIGHT :
240.34
WISWESSER LINE NOTATION :
ZR DNUNR DN1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
350 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
350 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - mouse Embryo
DOSE/DURATION :
10 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12,21,1988 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD:SUSPECTED CARCINOGEN DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,89,1971 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2093 No. of Facilities: 102 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 270 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS BX5020000
HS Code 2927000090

 Synthetic Route

~80%

N,N-DIMETHYL-4,4'-AZODIANILINE Structure

N,N-DIMETHYL-4,...

CAS#:539-17-3

Literature: Maatz, Gero; Maciollek, Arkadius; Ritter, Helmut Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 1929 - 1935

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N,N-DIMETHYL-4,4'-AZODIANILINE Structure

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CAS#:539-17-3

Literature: Journal of Materials Chemistry, , vol. 22, # 32 p. 16582 - 16589

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N,N-DIMETHYL-4,4'-AZODIANILINE Structure

N,N-DIMETHYL-4,...

CAS#:539-17-3

Literature: Journal of Biological Chemistry, , vol. 21, p. 150

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N,N-DIMETHYL-4,4'-AZODIANILINE Structure

N,N-DIMETHYL-4,...

CAS#:539-17-3

Literature: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, , vol. 260, # pt 1 p. 287 - 300

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N,N-DIMETHYL-4,4'-AZODIANILINE Structure

N,N-DIMETHYL-4,...

CAS#:539-17-3

Literature: Journal of Biological Chemistry, , vol. 21, p. 150

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N,N-DIMETHYL-4,4'-AZODIANILINE Structure

N,N-DIMETHYL-4,...

CAS#:539-17-3

Literature: Journal of the Chemical Society, , vol. 45, p. 116

 Customs

HS Code 2927000090
Summary 2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles2

More Articles
Chromogenic labeling of monosaccharides using 4'-N,N-dimethylamino-4-aminoazobenzene.

Anal. Biochem. 147(1) , 156-65, (1985)

Twenty-three monosaccharides, e.g., D- or L-pentoses, D- or L-hexoses, heptose, 2- or 6-deoxyhexoses, 2-deoxy-2-aminohexoses, hexuronic acids, and N-acetylmuramic acid, were coupled to the azo dye 4'-...

Chromogenic labeling of milk oligosaccharides: purification by affinity chromatography and structure determination.

Anal. Biochem. 173(1) , 1-9, (1988)

Oligosaccharides from human milk were derivatized with 4'-N,N-dimethylamino-4-amino-azobenzene (DAAB) by reductive amination and purified by affinity chromatography on immobilized antibodies followed ...

 Synonyms

N,N-Dimethyl-4,4'-azodianiline
MFCD00010204
N,N-Dimethyl-4,4′-azodianiline
4-[[4-(dimethylamino)phenyl]diazenyl]aniline
4-(4-Dimethylaminophenylazo)aniline
N,N-Dimethyl-4,4‘-azodianiline
EINECS 208-712-5
4-Amino-4'-dimethylaminoazobenzene