N,N-DIMETHYL-4,4'-AZODIANILINE
Names
[ CAS No. ]:
539-17-3
[ Name ]:
N,N-DIMETHYL-4,4'-AZODIANILINE
[Synonym ]:
N,N-Dimethyl-4,4'-azodianiline
MFCD00010204
N,N-Dimethyl-4,4′-azodianiline
4-[[4-(dimethylamino)phenyl]diazenyl]aniline
4-(4-Dimethylaminophenylazo)aniline
N,N-Dimethyl-4,4‘-azodianiline
EINECS 208-712-5
4-Amino-4'-dimethylaminoazobenzene
Chemical & Physical Properties
[ Density]:
1.11g/cm3
[ Boiling Point ]:
431.1ºC at 760mmHg
[ Melting Point ]:
190-195 °C (dec.)
[ Molecular Formula ]:
C14H16N4
[ Molecular Weight ]:
240.30400
[ Flash Point ]:
214.5ºC
[ Exact Mass ]:
240.13700
[ PSA ]:
53.98000
[ LogP ]:
4.33140
[ Index of Refraction ]:
1.595
[ Storage condition ]:
2-8°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BX5020000
- CHEMICAL NAME :
- Aniline, 4-(p-dimethylaminophenylazo)-
- CAS REGISTRY NUMBER :
- 539-17-3
- BEILSTEIN REFERENCE NO. :
- 0748253
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C14-H16-N4
- MOLECULAR WEIGHT :
- 240.34
- WISWESSER LINE NOTATION :
- ZR DNUNR DN1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis
MUTATION DATA
- TYPE OF TEST :
- Morphological transformation
- TEST SYSTEM :
- Rodent - mouse Embryo
- DOSE/DURATION :
- 10 mg/L
- REFERENCE :
- EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12,21,1988 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD:SUSPECTED CARCINOGEN DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,89,1971 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2093 No. of Facilities: 102 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 270 (estimated)
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ RTECS ]:
BX5020000
[ HS Code ]:
2927000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2927000090
[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Anal. Biochem. 147(1) , 156-65, (1985)
Twenty-three monosaccharides, e.g., D- or L-pentoses, D- or L-hexoses, heptose, 2- or 6-deoxyhexoses, 2-deoxy-2-aminohexoses, hexuronic acids, and N-acetylmuramic acid, were coupled to the azo dye 4'-...
Chromogenic labeling of milk oligosaccharides: purification by affinity chromatography and structure determination.Anal. Biochem. 173(1) , 1-9, (1988)
Oligosaccharides from human milk were derivatized with 4'-N,N-dimethylamino-4-amino-azobenzene (DAAB) by reductive amination and purified by affinity chromatography on immobilized antibodies followed ...