2-amino-4-methoxytoluene

Modify Date: 2024-01-08 14:10:50

2-amino-4-methoxytoluene Structure
2-amino-4-methoxytoluene structure
Common Name 2-amino-4-methoxytoluene
CAS Number 50868-72-9 Molecular Weight 137.179
Density 1.0±0.1 g/cm3 Boiling Point 252.2±20.0 °C at 760 mmHg
Molecular Formula C8H11NO Melting Point 43-46ºC
MSDS Chinese USA Flash Point 115.7±15.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 5-Methoxy-2-methylaniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 252.2±20.0 °C at 760 mmHg
Melting Point 43-46ºC
Molecular Formula C8H11NO
Molecular Weight 137.179
Flash Point 115.7±15.0 °C
Exact Mass 137.084061
PSA 35.25000
LogP 1.29
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.549
Water Solubility Slightly soluble in water.

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 5-Methoxy-2-methylaniline
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H302:Harmful if swallowed
H312:Harmful in contact with skin
H315:Causes skin irritation
H319:Causes serious eye irritation
Harmful if inhaled
H332:
H335:May cause respiratory irritation
P261:Avoid breathing dust/fume/gas/mist/vapours/spray
P280:Wear protective gloves/protective clothing/eye protection/face protection
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing

Section3. Composition/information on ingredients.
Ingredient name:5-Methoxy-2-methylaniline
CAS number:50868-72-9

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C8H11NO
Molecular weight: 137.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN2811Class: 6.1Packing group: III
Proper shipping name: TOXIC SOLIDS, ORGANIC, N.O.S. (5-Methoxy-2-methylaniline)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2922299090

 Customs

HS Code 2922299090
Summary 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
An expedient approach to the 2, 3, 5, 6-tetrasubstituted pyridine core of nosiheptide using oxidative cleavage of 2, 3, 5, 8-tetrasubstituted quinolines. Taddei D, et al.

ARKIVOC 11 , 56-63, (2007)

 Synonyms

5-methoxy-2-methyl aniline
5-methoxy-2-methylbenzenamine
2-Methyl-5-methoxyaniline
Benzenamine,5-methoxy-2-methyl
Benzenamine, 5-methoxy-2-methyl-
EINECS 256-816-4
6-Methyl-m-anisidine
3-methoxy-6-methyl-aniline
5-Methoxy-2-methylaniline
2-amino-4-methoxytoluene
MFCD00075057
5-methoxy-2-methylphenylamine
3-amino-4-methylanisole
5-Methoxy-o-toluidine