2-Biphenylylboronic acid
2-Biphenylylboronic acid structure
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Common Name | 2-Biphenylylboronic acid | ||
|---|---|---|---|---|
| CAS Number | 4688-76-0 | Molecular Weight | 198.03 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 404.0±38.0 °C at 760 mmHg | |
| Molecular Formula | C12H11BO2 | Melting Point | 167-172 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 198.1±26.8 °C | |
Use of 2-Biphenylylboronic acid2-Biphenylboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
| Name | 2-Biphenylboronic acid |
|---|---|
| Synonym | More Synonyms |
| Description | 2-Biphenylboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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| Related Catalog | |
| In Vitro | 2-Biphenylboronic acid 是一种底物，用于钯催化的与乙酸苄酯的交叉偶联，提供二芳基甲烷。它是参与与芳基卤化物、二溴乙烯基前体、烯基甲苯磺酸酯和甲磺酸酯以及喹啉羧酸酯的 Suzuki-Miyaura 交叉偶联反应的反应物。它参与用于合成手性四氢萘的分子内 Friedel-Crafts 烷基化、羟基化为酚类以及与炔烃的氧化偶联。 |
| Density | 1.2±0.1 g/cm3 |
|---|---|
| Boiling Point | 404.0±38.0 °C at 760 mmHg |
| Melting Point | 167-172 °C(lit.) |
| Molecular Formula | C12H11BO2 |
| Molecular Weight | 198.03 |
| Flash Point | 198.1±26.8 °C |
| Exact Mass | 198.085205 |
| PSA | 40.46000 |
| LogP | 3.35 |
| Vapour Pressure | 0.0±1.0 mmHg at 25°C |
| Index of Refraction | 1.610 |
| InChIKey | HYCYKHYFIWHGEX-UHFFFAOYSA-N |
| SMILES | OB(O)c1ccccc1-c1ccccc1 |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| Hazard Codes | C: Corrosive;Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 29310095 |
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~89%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Leermann, Timo; Leroux, Frederic R.; Colobert, Francoise Organic Letters, 2011 , vol. 13, # 17 p. 4479 - 4481 |
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~81%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Filthaus, Matthias; Oppel, Iris M.; Bettinger, Holger F. Organic and Biomolecular Chemistry, 2008 , vol. 6, # 7 p. 1201 - 1207 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Yabroff; Branch; Bettman Journal of the American Chemical Society, 1934 , vol. 56, p. 1850,1856 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Koyanagi, Masashi; Eichenauer, Nils; Ihara, Hideki; Yamamoto, Takeshi; Suginome, Michinori Chemistry Letters, 2013 , vol. 42, # 5 p. 541 - 543 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Huang, Helin; Chou, Ching-En; Che, Yanke; Li, Ligui; Wang, Chen; Yang, Xiaomei; Peng, Zhonghua; Zang, Ling Journal of the American Chemical Society, 2013 , vol. 135, # 44 p. 16490 - 16496 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Huang, Helin; Chou, Ching-En; Che, Yanke; Li, Ligui; Wang, Chen; Yang, Xiaomei; Peng, Zhonghua; Zang, Ling Journal of the American Chemical Society, 2013 , vol. 135, # 44 p. 16490 - 16496 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Koyanagi, Masashi; Eichenauer, Nils; Ihara, Hideki; Yamamoto, Takeshi; Suginome, Michinori Chemistry Letters, 2013 , vol. 42, # 5 p. 541 - 543 |
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~%
2-Biphenylylbor... CAS#:4688-76-0 |
| Literature: Gmelin Handbook: B: B-Verb.13, 4.5.3.3, page 160 - 167 |
![2-([1,1'-biphenyl]-2-yl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one structure](https://image.chemsrc.com/caspic/491/1449074-55-8.png)
| Precursor 9 | |
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| DownStream 10 | |
CAS#:321-60-8
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CAS#:2051-60-7![[1,1'-biphenyl]-2-carbonitrile structure](https://image.chemsrc.com/caspic/473/24973-49-7.png)
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CAS#:602-15-3| HS Code | 2931900090 |
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| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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Cross-coupling of benzylic acetates with arylboronic acids: one-pot transformation of benzylic alcohols to diarylmethanes.
Chem. Commun. (Camb.) , 5899, (2005) Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(eta3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diary... |
| (2-phenylphenyl)boronic acid |
| MFCD00136929 |
| Biphenyl-2-boronic acid |
| 2-Biphenylboronicacid |
| 2-Biphenylboronic Acid |
| Biphenyl-2-ylboronic acid |
| 1,1′-biphenyl-2-yl-boronic acid |
| Boronic acid, B-[1,1'-biphenyl]-2-yl- |
| 2-Biphenylylboronic acid |
| [1,1'-biphenyl]-2-ylboronic acid |
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- Shanghai Nianxing Industrial Co., Ltd
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- Product Name: 2-Biphenylylboronic acid
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- China
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