1-Chloro-2-methyl-1-oxopropan-2-yl acetate

Modify Date: 2024-01-04 10:13:38

1-Chloro-2-methyl-1-oxopropan-2-yl acetate Structure
1-Chloro-2-methyl-1-oxopropan-2-yl acetate structure
Common Name 1-Chloro-2-methyl-1-oxopropan-2-yl acetate
CAS Number 40635-66-3 Molecular Weight 164.587
Density 1.2±0.1 g/cm3 Boiling Point 178.8±23.0 °C at 760 mmHg
Molecular Formula C6H9ClO3 Melting Point N/A
MSDS Chinese USA Flash Point 68.3±0.0 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 1-Chlorocarbonyl-1-methylethyl acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 178.8±23.0 °C at 760 mmHg
Molecular Formula C6H9ClO3
Molecular Weight 164.587
Flash Point 68.3±0.0 °C
Exact Mass 164.024017
PSA 43.37000
LogP 1.25
Vapour Pressure 1.0±0.3 mmHg at 25°C
Index of Refraction 1.435
Storage condition 2-8°C

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Supplemental HS Reacts violently with water.
Precautionary Statements P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R14;R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2918199090

 Synthetic Route

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1-Chloro-2-methyl-1-oxopropan-2-yl acetate Structure

1-Chloro-2-meth...

CAS#:40635-66-3

Literature: Schirmeister-Tichy, Helga; Iacono, Kathryn T.; Muto, Nicholas F.; Homan, Joseph W.; Suhadolnik, Robert J.; Pfleiderer, Wolfgang Helvetica Chimica Acta, 1999 , vol. 82, # 4 p. 597 - 613

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1-Chloro-2-methyl-1-oxopropan-2-yl acetate Structure

1-Chloro-2-meth...

CAS#:40635-66-3

Literature: Greenberg; Moffatt Journal of the American Chemical Society, 1973 , vol. 95, # 12 p. 4016 - 4025 Title/Abstract Full Text View citing articles Show Details Friary,A. Journal of Heterocyclic Chemistry, 1978 , vol. 15, p. 63 - 64

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1-Chloro-2-methyl-1-oxopropan-2-yl acetate Structure

1-Chloro-2-meth...

CAS#:40635-66-3

Literature: Kirillov,A.I.; Ivanova,L.F. Journal of Organic Chemistry USSR (English Translation), 1973 , vol. 9, p. 2258 - 2261 Zhurnal Organicheskoi Khimii, 1973 , vol. 9, p. 2241 - 2245

 Customs

HS Code 2918199090
Summary 2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles2

More Articles
Efficient synthesis of some dichloroalditols: direct regioselective chlorination of some unprotected alditols by 1-chlorocarbonyl-1-methylethyl acetate. Benazza M, et al.

J. Carbohydr. Chem. 13(7) , 967-79, (1994)

Highly diastereoselective synthesis of nucleoside adducts from the carcinogenic benzo[a]pyrene diol epoxide and a computational analysis.

J. Am. Chem. Soc. 129(1) , 68-76, (2007)

A diastereoselective synthesis of the nucleoside adducts corresponding to a cis ring-opening of the carcinogen (+/-)-7 beta, 8 alpha-dihydroxy-9 alpha,10 alpha-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene ...

 Synonyms

2-acetoxyisobutyryl chloride (α-acetoxy-isobutyryl chloride)
Acetic acid, 1-chlorocarbonyl-1-methylethyl ester
2-Acetoxyisobutyryl Chloride
1-Chloro-2-methyl-1-oxo-2-propanyl acetate
2-Acetoxy-2-methylpropionyl Chloride
(1-chloro-2-methyl-1-oxopropan-2-yl) acetate
1-Chloro-2-methyl-1-oxopropan-2-yl acetate
Chlorocarbonyl-1-methylethyl acetate
2-Chloro-1,1-dimethyl-2-oxoethyl acetate
Propanoyl chloride, 2-(acetyloxy)-2-methyl-
MFCD00000708
EINECS 255-016-2