(2S)-2-Bromopropanoic acid

Modify Date: 2024-01-02 19:25:07

(2S)-2-Bromopropanoic acid Structure
(2S)-2-Bromopropanoic acid structure
Common Name (2S)-2-Bromopropanoic acid
CAS Number 32644-15-8 Molecular Weight 152.975
Density 1.8±0.1 g/cm3 Boiling Point 202.6±13.0 °C at 760 mmHg
Molecular Formula C3H5BrO2 Melting Point -35ºC(lit.)
MSDS Chinese USA Flash Point 100.0±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name (2S)-2-bromopropanoic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.8±0.1 g/cm3
Boiling Point 202.6±13.0 °C at 760 mmHg
Melting Point -35ºC(lit.)
Molecular Formula C3H5BrO2
Molecular Weight 152.975
Flash Point 100.0±0.0 °C
Exact Mass 151.947281
PSA 37.30000
LogP 0.85
Vapour Pressure 0.1±0.8 mmHg at 25°C
Index of Refraction 1.496
Storage condition 2-8°C

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;
Risk Phrases R22;R34
Safety Phrases 26-36/37/39-45
RIDADR UN 3265
WGK Germany 3
Packaging Group III
HS Code 2915900090

 Synthetic Route

~85%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: UNIVERSITY OF VIRGINIA PATENT FOUNDATION Patent: WO2007/117404 A2, 2007 ; Location in patent: Page/Page column 24-27 ;

~71%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Boyes, Scott A.; Hewson, Alan T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 16 p. 2759 - 2765

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Chemical Communications, , # 35 p. 4432 - 4434

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Tetrahedron Letters, , vol. 42, # 34 p. 5985 - 5987

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Chemische Berichte, , vol. 33, p. 3355 Justus Liebigs Annalen der Chemie, , vol. 349, p. 325 Justus Liebigs Annalen der Chemie, , vol. 370, p. 236,237 Justus Liebigs Annalen der Chemie, , vol. 340, p. 171 Bulletin des Societes Chimiques Belges, , vol. 46, p. 485

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Tetrahedron: Asymmetry, , vol. 6, # 8 p. 1919 - 1932

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Justus Liebigs Annalen der Chemie, , vol. 370, p. 236,237 Justus Liebigs Annalen der Chemie, , vol. 340, p. 171 Justus Liebigs Annalen der Chemie, , vol. 349, p. 325 Chemische Berichte, , vol. 33, p. 3354

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Justus Liebigs Annalen der Chemie, , vol. 340, p. 171

~%

(2S)-2-Bromopropanoic acid Structure

(2S)-2-Bromopro...

CAS#:32644-15-8

Literature: Chemische Berichte, , vol. 40, p. 491 Chemische Berichte, , vol. 39, p. 3988 Chem. Zentralbl., , vol. 77, # II p. 60 Justus Liebigs Annalen der Chemie, , vol. 340, p. 171 Chemische Berichte, , vol. 49, p. 2456

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles5

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Structure and synthesis of histopine, a histidine derivative produced by crown gall tumors.

Biochemistry 23 , 3287, (1984)

Histopine, an unusual amino acid derivative of histidine isolated from crown gall tumors of sunflowers (Helianthus annus) inoculated with Agrobacterium tumefaciens strain B6, was previously assigned t...

M. Harfenist et al.

J. Org. Chem. 50 , 1356, (1985)

H.G. Lerchen, H. Kunz

Tetrahedron Lett. 26 , 5257, (1985)

 Synonyms

Propanoic acid, 2-bromo-, (2S)-
(S)-2-Bromopropanoic acid
QVYE1 &&S Form
(S)-(-)-2-BroMopropionic Acid
sGPhCQbILuSRX@
L-2-Bromopropionic Acid
(2S)-2-Bromopropanoic acid
MFCD00137325
S-2-Bromopropionic acid
(S)-2-bromo propanoic acid