UNII:120GN9C472

Modify Date: 2024-01-02 16:31:16

UNII:120GN9C472 Structure
UNII:120GN9C472 structure
 Common Name UNII:120GN9C472
CAS Number 2455-24-5 Molecular Weight 170.206
Density 1.0±0.1 g/cm3 Boiling Point 265.0±0.0 °C at 760 mmHg
Molecular Formula C9H14O3 Melting Point N/A
MSDS USA Flash Point 105.6±14.4 °C

 Names

Name oxolan-2-ylmethyl 2-methylprop-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 265.0±0.0 °C at 760 mmHg
Molecular Formula C9H14O3
Molecular Weight 170.206
Flash Point 105.6±14.4 °C
Exact Mass 170.094299
PSA 35.53000
LogP 1.38
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.453

 MSDS

Tetrahydrofurfuryl Methacrylate (stabilized with MEHQ) Revision number: 5
SAFETY DATA SHEET
Section1. IDENTIFICATION
Product name:Tetrahydrofurfuryl Methacrylate (stabilized with MEHQ)

Revision number:5
Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS
Skin corrosion/irritationCategory 2
Category 2A
Serious eye damage/eye irritation
ENVIRONMENTAL HAZARDSNot classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal wordWarning
Hazard statementsCauses skin irritation
Causes serious eye irritation
Precautionary statements:
Wash hands thoroughly after handling.
[Prevention]
Wear protective gloves/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
[Response]
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
May cause polimerization.
Other hazards which do not
result in classification
Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:Tetrahydrofurfuryl Methacrylate (stabilized with MEHQ)
Percent:>95.0%(GC)
CAS Number:2455-24-5
Synonyms:Methacrylic Acid Tetrahydrofurfuryl Ester
Chemical Formula:C9H14O3
MEHQ)
Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.
Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Unsuitable extinguishing Solid streams of water
media:
Specific hazards arising This substance may polimerize explosively when heated or involved in a fire.
from the chemical:Container may explode when heated. Combat fire from a sheltered position.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water. Eliminate all ignition sources if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:
Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
emergency procedures: around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into a
containment and cleaning covered container. In case of large amount of spillage, contain a spill by bunding.
up: Adhered or collected material should be promptly disposed of, in accordance with
appropriate laws and regulations.
Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Wash hands and face thoroughly after
handling.
Use a ventilation, local exhaust if vapour or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Store in a cool and dark place.
Storage conditions:
Store away from incompatible materials such as oxidizing agents.
Light-sensitive
Packaging material:Comply with laws.
Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Vapor respirator. Follow local and national regulations.
Protective gloves.
Hand protection:
MEHQ)
Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.
Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Liquid
Form:Clear
Colour:Colorless - Very pale yellow
Odour:No data available
pH: No data available
Melting point/freezing point:No data available
Boiling point/range:85°C/0.5kPa
Flash point:96°C
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:1.04
Solubility(ies):
[Water]No data available
[Other solvents]No data available
Section10. STABILITY AND REACTIVITY
Chemical stability:Polymerization may occur under the influences of heat, light or on contact with
polymelization initiators such as peroxides etc.
Possibility of hazardous No special reactivity has been reported.
reactions:
Conditions to avoid:Heat, Light
Incompatible materials: Oxidizing agents, Reducing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:
Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available
Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea:No data available
No data available
Algae:
Persistence / degradability: No data available
No data available
Bioaccumulative
potential(BCF):
Mobility in soil
Log Pow:No data available
No data available
Soil adsorption (Koc):
Henry's LawNo data available
constant(PaM3/mol):
MEHQ)
Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.
Section14. TRANSPORT INFORMATION
Hazards Class:Does not correspond to the classification standard of the United Nations
Not listed
UN-No:
Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Hazard Codes Xi
Risk Phrases R10;R36/37/38
Safety Phrases S36
RIDADR 3272
WGK Germany 1
Packaging Group III
Hazard Class 3
HS Code 2932190090

 Synthetic Route

Tetrahydrofurfuryl alcohol structure

Tetrahydrofurfu...

CAS#:97-99-4

Methyl methacrylate structure

Methyl methacrylate

CAS#:80-62-6

~%

UNII:120GN9C472 Structure

UNII:120GN9C472

CAS#:2455-24-5

Literature: US2129666 , ;
Tetrahydrofurfuryl alcohol structure

Tetrahydrofurfu...

CAS#:97-99-4

Ethyl methacrylate structure

Ethyl methacrylate

CAS#:97-63-2

~%

UNII:120GN9C472 Structure

UNII:120GN9C472

CAS#:2455-24-5

Literature: Journal of Organic Chemistry, , vol. 14, p. 1094,1095, 1097

 Customs

HS Code 2932190090
Summary 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

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 Synonyms

SR 203
EINECS 219-529-5
Methacrylic Acid Tetrahydrofurfuryl Ester
Methacrylsaeure-tetrahydrofurfurylester
Sartomer SR 203
UNII:120GN9C472
Tetrahydro-2-furanylmethyl methacrylate
MFCD00014515
2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester
tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate
Tetrahydrofuran-2-ylmethyl methacrylate
Tetrahydrofurfuryl Methacrylate
2-methyl-propenoic acid tetrahydrofuranyl-methyl ester
Methacrylic acid, tetrahydrofurfuryl ester (8CI)
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