((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

Modify Date: 2024-01-10 23:53:06

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure
((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate structure
Common Name ((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate
CAS Number 23788-74-1 Molecular Weight 286.344
Density 1.2±0.1 g/cm3 Boiling Point 400.1±25.0 °C at 760 mmHg
Molecular Formula C13H18O5S Melting Point 41-43 °C(lit.)
MSDS Chinese USA Flash Point 195.8±23.2 °C

 Names

Name [(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 400.1±25.0 °C at 760 mmHg
Melting Point 41-43 °C(lit.)
Molecular Formula C13H18O5S
Molecular Weight 286.344
Flash Point 195.8±23.2 °C
Exact Mass 286.087494
PSA 70.21000
LogP 1.58
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.507
Storage condition −20°C

 Safety Information

Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn: Harmful;Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2932999099

 Synthetic Route

~96%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Dams, Iwona; Chodynski, Michal; Krupa, Malgorzata; Pietraszek, Anita; Zezula, Marta; Cmoch, Piotr; Kosinska, Monika; Kutner, Andrzej Tetrahedron, 2013 , vol. 69, # 5 p. 1634 - 1648

~%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, , vol. 41, # 3 p. 586 - 592

~93%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Tsuda; Okada; Tanaka; Shigematsu; Hori; Goto; Hashimoto Chemical and Pharmaceutical Bulletin, 1991 , vol. 39, # 3 p. 607 - 611

~%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Journal of Medicinal Chemistry, , vol. 27, # 9 p. 1142 - 1149

~86%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Tsuda, Yoshisuke; Yoshimoto, Kimihiro; Nishikawa, Terumi Chemical & Pharmaceutical Bulletin, 1981 , vol. 29, # 12 p. 3593 - 3600

~%

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate Structure

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Angewandte Chemie, , vol. 92, # 3 p. 201 - 202

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles3

More Articles
C. André et al.

Tetrahedron Asymmetry 9 , 1359, (1998)

K.C. Nicolaou et al.

J. Chem. Soc. Chem. Commun. , 349, (1984)

S.K. Bhatia, J. Hajdu

Tetrahedron Lett. 28 , 1729, (1987)

 Synonyms

(R)-(-)-2,2-dimethyl-4-tosyloxymethyl-1,3-dioxolane
(R)-(-)-2,2-dimethyl-4-(hydroxymethyl)-1,3-dioxolane-p-toluenesulfonate
(R)-2,2-dimethyl-1,3-dioxolan-4-methanol toluene-4-sulfonate
MFCD00063233
(R)-2,2-Dimethyl-1,3-dioxolane-4-methanol p-toluenesulfonate
[(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate
1,3-Dioxolane-4-methanol, 2,2-dimethyl-, 4-methylbenzenesulfonate, (4R)-
(R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl toluene-4-sulfonate
(R)-1-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methyl-benzenesulfonate
(4R)-2,2-dimethyl-4-(4-toluenesulphonyloxymethyl)-1,3-dioxolane
(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE
(R)-(-)-2,2-Dimethyl-1,3-dioxolan-4-ylmethylp-Toluenesulfonate
(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-ylmethyl-p-toluenesulfonate
(R)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl p-tosylate
1,2-Isopropylidene-sn-glycerol 3-tosylate
(R)-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)METHYL-4-METHYLBENZENESULFONATE
((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate
p-Toluenesulfonic acid [(R)-2,2-dimethyl-1,3-dioxolane-4β-yl]methyl ester
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