dibutyltin bis(2,4-pentanedionate)

Modify Date: 2024-01-02 10:56:57

dibutyltin bis(2,4-pentanedionate) Structure
dibutyltin bis(2,4-pentanedionate) structure
Common Name dibutyltin bis(2,4-pentanedionate)
CAS Number 22673-19-4 Molecular Weight 431.14500
Density 1.22 g/mL at 25 °C(lit.) Boiling Point 132ºC (0.4 torr)
Molecular Formula C18H32O4Sn Melting Point 26ºC
MSDS Chinese USA Flash Point 71.9ºC
Symbol GHS02 GHS05 GHS07 GHS08 GHS09
GHS02, GHS05, GHS07, GHS08, GHS09
Signal Word Danger

 Use of dibutyltin bis(2,4-pentanedionate)




 Names

Name (Z)-4-oxopent-2-en-2-olate,pentane,tin(4+)
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.22 g/mL at 25 °C(lit.)
Boiling Point 132ºC (0.4 torr)
Melting Point 26ºC
Molecular Formula C18H32O4Sn
Molecular Weight 431.14500
Flash Point 71.9ºC
Exact Mass 432.13200
PSA 52.60000
LogP 5.04760
Appearance of Characters liquid | pale yellow to amber
Index of Refraction n20/D 1.5110(lit.)

 MSDS


Section 1: Product Identification
Chemical Name:Di-n-butyltinbis(acetylacetonate)
CAS Registry Number:22673-19-4
Formula:(C4H9)2Sn(CH3COCHCOCH3)2
EINECS Number:none
Chemical Family:organotin compound
Synonym:Di-n-butyltinbis(2,4-pentandionate)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound22673-19-4100%0.1mg/m3 (as Sn-0.1mg/m3 (as Sn-

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Ingestion may lead to gastrointestinal cramps, nausea and
Emergency Overview:
diarrhea.
Primary Routes of Exposure:Ingestion, skin, eyes
Eye Contact:Causes mild irritation of the eyes.
Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
Skin Contact:
severe irritation.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Irritating to mouth throat and stomach. Ingestion may lead to gastrointestinal cramps, nausea and diarrhea.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long term chromic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim will need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:not determined
Explosion Limits:not determined
Extinguishing Medium:dry chemical, carbon dioxide, water spray or foam.
If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing and full protective clothing.
Hazardous Combustion andcarbon dioxide, carbon monoxide, soot, organic fumes and tin compounds.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be absorbed into vermiculite or other suitable adsorbent. Larger spills must be contained in
Spill and Leak Procedures:order to avoid contamination of the soil, sewers systems or bodies of water. Absorb the material into clay,
sawdust or other suitable adsorbent.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed.

SECTION 8: Exposure Controls and Personal Protection
Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional
Eye Protection:
protection.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:pale yellow to amber liquid
Molecular Weight:431.16
Melting Point:26°
Boiling Point:150°C /3mm
Vapor Pressure:no data
Specific Gravity:1.21
Odor:mild odor
Solubility in Water:Decomposes in water

SECTION 10: Stability and Reactivity
Stability:air and moisture-stable liquid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:None
Incompatibility:Strong acids, strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and tin compounds.

SECTION 11: Toxicological Information
RTECS Data:No specific information available in the RTECS files. Alkyltin compounds are generally considered toxic.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS08 GHS09
GHS02, GHS05, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H228-H302-H314-H317-H341-H360-H370-H372-H410
Precautionary Statements P201-P210-P260-P280-P305 + P351 + P338-P308 + P311
Target Organs thymus gland
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn: Harmful;
Risk Phrases 10-20/21/22-36/37/38-63
Safety Phrases 16-26-36
RIDADR UN 3178 4.1/PG 2
WGK Germany 2
Packaging Group II
Hazard Class 6.1

 Preparation


 Synonyms

EINECS 245-152-0
MFCD00077994
Dibutylbis(pentane-2,4-dionato-O,O')tin
Tin,dibutylbis(2,4-pentanedionato-O,O')-,(OC-6-11)
Sn(acac)Bu2