22673-19-4

22673-19-4 structure
22673-19-4 structure

Name (Z)-4-oxopent-2-en-2-olate,pentane,tin(4+)
Synonyms EINECS 245-152-0
MFCD00077994
Dibutylbis(pentane-2,4-dionato-O,O')tin
Tin,dibutylbis(2,4-pentanedionato-O,O')-,(OC-6-11)
Sn(acac)Bu2
Density 1.22 g/mL at 25 °C(lit.)
Boiling Point 132ºC (0.4 torr)
Melting Point 26ºC
Molecular Formula C18H32O4Sn
Molecular Weight 431.14500
Flash Point 71.9ºC
Exact Mass 432.13200
PSA 52.60000
LogP 5.04760
Appearance liquid | pale yellow to amber
Index of Refraction n20/D 1.5110(lit.)

Section 1: Product Identification
Chemical Name:Di-n-butyltinbis(acetylacetonate)
CAS Registry Number:22673-19-4
Formula:(C4H9)2Sn(CH3COCHCOCH3)2
EINECS Number:none
Chemical Family:organotin compound
Synonym:Di-n-butyltinbis(2,4-pentandionate)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound22673-19-4100%0.1mg/m3 (as Sn-0.1mg/m3 (as Sn-

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Ingestion may lead to gastrointestinal cramps, nausea and
Emergency Overview:
diarrhea.
Primary Routes of Exposure:Ingestion, skin, eyes
Eye Contact:Causes mild irritation of the eyes.
Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
Skin Contact:
severe irritation.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Irritating to mouth throat and stomach. Ingestion may lead to gastrointestinal cramps, nausea and diarrhea.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long term chromic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim will need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:not determined
Explosion Limits:not determined
Extinguishing Medium:dry chemical, carbon dioxide, water spray or foam.
If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing and full protective clothing.
Hazardous Combustion andcarbon dioxide, carbon monoxide, soot, organic fumes and tin compounds.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be absorbed into vermiculite or other suitable adsorbent. Larger spills must be contained in
Spill and Leak Procedures:order to avoid contamination of the soil, sewers systems or bodies of water. Absorb the material into clay,
sawdust or other suitable adsorbent.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed.

SECTION 8: Exposure Controls and Personal Protection
Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional
Eye Protection:
protection.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:pale yellow to amber liquid
Molecular Weight:431.16
Melting Point:26°
Boiling Point:150°C /3mm
Vapor Pressure:no data
Specific Gravity:1.21
Odor:mild odor
Solubility in Water:Decomposes in water

SECTION 10: Stability and Reactivity
Stability:air and moisture-stable liquid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:None
Incompatibility:Strong acids, strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and tin compounds.

SECTION 11: Toxicological Information
RTECS Data:No specific information available in the RTECS files. Alkyltin compounds are generally considered toxic.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS02 GHS05 GHS07 GHS08 GHS09
GHS02, GHS05, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H228-H302-H314-H317-H341-H360-H370-H372-H410
Precautionary Statements P201-P210-P260-P280-P305 + P351 + P338-P308 + P311
Target Organs thymus gland
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn: Harmful;
Risk Phrases 10-20/21/22-36/37/38-63
Safety Phrases 16-26-36
RIDADR UN 3178 4.1/PG 2
WGK Germany 2
Packaging Group II
Hazard Class 6.1