1-Bromo-3-(trifluoromethoxy)benzene

Modify Date: 2024-01-02 19:21:30

1-Bromo-3-(trifluoromethoxy)benzene Structure
1-Bromo-3-(trifluoromethoxy)benzene structure
Common Name 1-Bromo-3-(trifluoromethoxy)benzene
CAS Number 2252-44-0 Molecular Weight 241.005
Density 1.7±0.1 g/cm3 Boiling Point 161.9±35.0 °C at 760 mmHg
Molecular Formula C7H4BrF3O Melting Point N/A
MSDS Chinese USA Flash Point 62.8±0.0 °C

 Names

Name 3-(Trifluoromethoxy)bromobenzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 161.9±35.0 °C at 760 mmHg
Molecular Formula C7H4BrF3O
Molecular Weight 241.005
Flash Point 62.8±0.0 °C
Exact Mass 239.939758
PSA 9.23000
LogP 4.06
Vapour Pressure 2.9±0.3 mmHg at 25°C
Index of Refraction 1.475

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Hazard Codes Xi:Irritant
Risk Phrases R36/37/38
Safety Phrases S37/39-S26
WGK Germany 3
HS Code 2909309090

 Synthetic Route

~37%

1-Bromo-3-(trifluoromethoxy)benzene Structure

1-Bromo-3-(trif...

CAS#:2252-44-0

Literature: MITENI S.P.A. Patent: WO2007/107820 A2, 2007 ; Location in patent: Page/Page column 9 ;

~33%

1-Bromo-3-(trifluoromethoxy)benzene Structure

1-Bromo-3-(trif...

CAS#:2252-44-0

Literature: MITENI S.P.A. Patent: WO2007/107820 A2, 2007 ; Location in patent: Page/Page column 8-9 ;

~%

1-Bromo-3-(trifluoromethoxy)benzene Structure

1-Bromo-3-(trif...

CAS#:2252-44-0

Literature: WO2007/107820 A2, ; Page/Page column 7 ;

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
1, 2-Didehydro-3-and-4-(trifluoromethoxy) benzene: The “Aryne” Route to 1-and 2-(Trifluoromethoxy) naphthalenes. Schlosser M and Castagnetti E.

European J. Org. Chem. 21 , 3991-97, (2001)

The use of arynes in organic synthesis. Pellissier H and Santelli M.

Tetrahedron 59(6) , 701-30, (2003)

A new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep and its application in asymmetric hydrogenation. Zhang D-Y, et al.

Tetrahedron Lett. 53(20) , 2556-59, (2012)

 Synonyms

3-Bromo-α,α,α-trifluoroanisole
3-Bromo-1-(trifluoromethoxy)benzene
1-Bromo-3-(trifluoromethoxy)benzene
3-(Trifluoromethoxy)bromobenzene
3-Bromo(trifluoromethoxy)benzene
m-bromophenyl trifluoromethyl ether
FXFFOR CE
MFCD00040943
M-BROMO(TRIFLUOROMETHOXY)BENZENE
Benzene, 1-bromo-3-(trifluoromethoxy)-
3-Bromophenyl trifluoromethyl ether