1-Bromo-3-(trifluoromethoxy)benzene

Names

[ Name ]:
1-Bromo-3-(trifluoromethoxy)benzene

[Synonym ]:
3-Bromo-α,α,α-trifluoroanisole
3-Bromo-1-(trifluoromethoxy)benzene
1-Bromo-3-(trifluoromethoxy)benzene
3-(Trifluoromethoxy)bromobenzene
3-Bromo(trifluoromethoxy)benzene
m-bromophenyl trifluoromethyl ether
FXFFOR CE
MFCD00040943
M-BROMO(TRIFLUOROMETHOXY)BENZENE
Benzene, 1-bromo-3-(trifluoromethoxy)-
3-Bromophenyl trifluoromethyl ether

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
161.9±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₄BrF₃O

[ Molecular Weight ]:
241.005

[ Flash Point ]:
62.8±0.0 °C

[ Exact Mass ]:
239.939758

[ PSA ]:
9.23000

[ LogP ]:
4.06

[ Vapour Pressure ]:
2.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.475

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

1, 2-Didehydro-3-and-4-(trifluoromethoxy) benzene: The “Aryne” Route to 1-and 2-(Trifluoromethoxy) naphthalenes. Schlosser M and Castagnetti E.

European J. Org. Chem. 21 , 3991-97, (2001)

The use of arynes in organic synthesis. Pellissier H and Santelli M.

Tetrahedron 59(6) , 701-30, (2003)

A new electronically deficient atropisomeric diphosphine ligand (S)-CF₃O-BiPhep and its application in asymmetric hydrogenation. Zhang D-Y, et al.

Tetrahedron Lett. 53(20) , 2556-59, (2012)