2-Bromo-4'-cyanoacetophenone
2-Bromo-4'-cyanoacetophenone structure
|
Common Name | 2-Bromo-4'-cyanoacetophenone | ||
|---|---|---|---|---|
| CAS Number | 20099-89-2 | Molecular Weight | 224.054 | |
| Density | 1.6±0.1 g/cm3 | Boiling Point | 342.4±22.0 °C at 760 mmHg | |
| Molecular Formula | C9H6BrNO | Melting Point | 92-96 °C(lit.) | |
| MSDS | USA | Flash Point | 160.9±22.3 °C | |
| Symbol |
GHS05, GHS07 |
Signal Word | Danger | |
| Name | 4-(2-bromoacetyl)benzonitrile |
|---|---|
| Synonym | More Synonyms |
| Density | 1.6±0.1 g/cm3 |
|---|---|
| Boiling Point | 342.4±22.0 °C at 760 mmHg |
| Melting Point | 92-96 °C(lit.) |
| Molecular Formula | C9H6BrNO |
| Molecular Weight | 224.054 |
| Flash Point | 160.9±22.3 °C |
| Exact Mass | 222.963272 |
| PSA | 40.86000 |
| LogP | 1.75 |
| Vapour Pressure | 0.0±0.8 mmHg at 25°C |
| Index of Refraction | 1.590 |
| InChIKey | LJANCPRIUMHGJE-UHFFFAOYSA-N |
| SMILES | N#Cc1ccc(C(=O)CBr)cc1 |
| Symbol |
GHS05, GHS07 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H302-H312-H314-H332 |
| Precautionary Statements | P280-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| Hazard Codes | C:Corrosive; |
| Risk Phrases | R20/21/22;R34 |
| Safety Phrases | S26-S27-S36/37/39-S45 |
| RIDADR | UN 2928 6.1/PG 2 |
| WGK Germany | 3 |
| Packaging Group | II |
| Hazard Class | 6.1 |
| HS Code | 2926909090 |
|
~99%
2-Bromo-4'-cyan... CAS#:20099-89-2 |
| Literature: Kallmayer, Hans-Joerg; Wagner, Eugen Archiv der Pharmazie (Weinheim, Germany), 1980 , vol. 313, # 4 p. 315 - 323 |
|
~45%
2-Bromo-4'-cyan... CAS#:20099-89-2 |
| Literature: Journal of Medicinal Chemistry, , vol. 54, # 12 p. 4042 - 4056 |
|
~65%
2-Bromo-4'-cyan... CAS#:20099-89-2 |
| Literature: Chen, Zheng-Wang; Ye, Dong-Nai; Ye, Min; Zhou, Zhong-Gao; Li, Shen-Huan; Liu, Liang-Xian Tetrahedron Letters, 2014 , vol. 55, # 7 p. 1373 - 1375 |
|
~59%
2-Bromo-4'-cyan... CAS#:20099-89-2 |
| Literature: Tada, Norihiro; Ban, Kazunori; Hirashima, Shin-Ichi; Miura, Tsuyoshi; Itoh, Akichika Organic and Biomolecular Chemistry, 2010 , vol. 8, # 20 p. 4701 - 4704 |
|
~33%
2-Bromo-4'-cyan... CAS#:20099-89-2 |
| Literature: Tetrahedron Letters, , vol. 53, # 2 p. 191 - 195 |
| Precursor 3 | |
|---|---|
| DownStream 10 | |
![4-IMIDAZO[1,2-A]PYRIMIDIN-2-YL-BENZONITRILE structure](https://image.chemsrc.com/caspic/057/104691-51-2.png)
CAS#:104691-51-2
CAS#:436151-85-8
CAS#:20099-53-0
CAS#:60207-22-9
CAS#:13367-81-2
CAS#:101219-69-6
CAS#:3490-50-4
CAS#:34443-07-7
CAS#:85554-13-8| HS Code | 2926909090 |
|---|---|
| Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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Direct synthesis of α-bromoketones from alkylarenes by aerobic visible light photooxidation.
Org. Biomol. Chem. 8(20) , 4701-4, (2010) The direct synthesis of α-bromoketones from alkylarenes by aerobic photooxidation with hydrobromic acid is reported. The key success for this direct oxidative reaction is due to control of bromination... |
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Application of DMF–methyl sulfate adduct in the regioselective synthesis of 3-acylated indolizines. Przewloka T, et al.
Tetrahedron Lett. 48(33) , 5739-5742, (2007)
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Synthesis and antifungal activity of novel thiazole-containing triazole antifungals. II. Optically active ER-30346 and its derivatives. Tsuruoka, Akihiko, et al.
Chem. Pharm. Bull. 46(4) , 623-630, (1998)
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| 2-bromo-4'-cyano-acetophenone |
| Benzonitrile, 4-(bromoacetyl)- |
| MFCD00052931 |
| 4-(Bromacetyl)benzolcarbonitril |
| 2-bromo-4'-CN-acetophenone |
| 4-(Bromoacetyl)benzonitrile |
| 2-Bromo-4'-cyanoacetophenone |
| p-Cyanophenacyl bromide |
| 2-Br-4'-CN-acetophenone |
| 4-(2-Bromoacetyl)benzonitrile |
| 4-Cyanophenacyl bromide |
| Benzonitrile, 4-(2-bromoacetyl)- |
| 4-(2-bromo-acetyl)-benzonitrile |
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- Shanghai Nianxing Industrial Co., Ltd
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- China
- Product Name: 2-Bromo-4'-cyanoacetophenone
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