Furan,tetrahydro-2-(methoxymethyl)-

Modify Date: 2024-01-03 11:40:15

Furan,tetrahydro-2-(methoxymethyl)- Structure
Furan,tetrahydro-2-(methoxymethyl)- structure
Common Name Furan,tetrahydro-2-(methoxymethyl)-
CAS Number 19354-27-9 Molecular Weight 116.15800
Density 0.939g/cm3 Boiling Point 140ºC at 760mmHg
Molecular Formula C6H12O2 Melting Point N/A
MSDS N/A Flash Point 33.3ºC

 Names

Name 2-(methoxymethyl)oxolane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.939g/cm3
Boiling Point 140ºC at 760mmHg
Molecular Formula C6H12O2
Molecular Weight 116.15800
Flash Point 33.3ºC
Exact Mass 116.08400
PSA 18.46000
LogP 0.81180
Vapour Pressure 7.79mmHg at 25°C
Index of Refraction 1.425-1.427

 MSDS

Name: Methyl tetrahydrofurfuryl ether Material Safety Data Sheet
Synonym:
CAS: 19354-27-9
Section 1 - Chemical Product MSDS Name:Methyl tetrahydrofurfuryl ether Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
19354-27-9 Methyl tetrahydrofurfuryl ether 100 242-986-7
Hazard Symbols: None Listed.
Risk Phrases: 10

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 19354-27-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Colorless Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 140 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 33 deg C ( 91.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9520g/cm3
Molecular Formula: C6H12O2
Molecular Weight: 116.16

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 19354-27-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl tetrahydrofurfuryl ether - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 19354-27-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 19354-27-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19354-27-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases 10
Safety Phrases S16
RIDADR UN 3271
Packaging Group III
Hazard Class 3.2
HS Code 2932190090

 Synthetic Route

~%

Furan,tetrahydro-2-(methoxymethyl)- Structure

Furan,tetrahydr...

CAS#:19354-27-9

Literature: Journal of Physical Organic Chemistry, , vol. 8, p. 1 - 4

~66%

Furan,tetrahydro-2-(methoxymethyl)- Structure

Furan,tetrahydr...

CAS#:19354-27-9

Literature: Pandey, Ganesh; Soma Sekhar, B. B. V. Journal of Organic Chemistry, 1994 , vol. 59, # 24 p. 7367 - 7372

~77%

Furan,tetrahydro-2-(methoxymethyl)- Structure

Furan,tetrahydr...

CAS#:19354-27-9

Literature: Pandey, Ganesh; Soma Sekhar, B. B. V. Journal of Organic Chemistry, 1994 , vol. 59, # 24 p. 7367 - 7372

~%

Furan,tetrahydro-2-(methoxymethyl)- Structure

Furan,tetrahydr...

CAS#:19354-27-9

Literature: Journal of the American Chemical Society, , vol. 52, p. 3251,3252 Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, , vol. 152, p. 378,399

~%

Furan,tetrahydro-2-(methoxymethyl)- Structure

Furan,tetrahydr...

CAS#:19354-27-9

Literature: Journal of the American Chemical Society, , vol. 52, p. 3251,3252

~%

Detail
Literature: Green Chemistry, , vol. 16, # 2 p. 708 - 718

 Customs

HS Code 2932190090
Summary 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

2-(Methoxymethyl)tetrahydrofuran
Methyl tetrahydrofurfuryl ether
methyltetrahydrofurufuryl ether
tetrahydrofurfuryl methyl ether
tetrahydro-2-methoxymethylfuran
EINECS 242-986-7
Furan,tetrahydro-2-(methoxymethyl)