2-bromo-1-(4-chlorophenyl)-2-phenylethanone

Modify Date: 2024-01-10 23:25:16

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure
2-bromo-1-(4-chlorophenyl)-2-phenylethanone structure
Common Name 2-bromo-1-(4-chlorophenyl)-2-phenylethanone
CAS Number 1889-78-7 Molecular Weight 309.58600
Density 1.491g/cm3 Boiling Point 387.3ºC at 760mmHg
Molecular Formula C14H10BrClO Melting Point 65ºC
MSDS N/A Flash Point 188ºC

 Names

Name 2-bromo-1-(4-chlorophenyl)-2-phenylethanone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.491g/cm3
Boiling Point 387.3ºC at 760mmHg
Melting Point 65ºC
Molecular Formula C14H10BrClO
Molecular Weight 309.58600
Flash Point 188ºC
Exact Mass 307.96000
PSA 17.07000
LogP 4.65890
Vapour Pressure 3.33E-06mmHg at 25°C
Index of Refraction 1.625
Storage condition 2-8°C

 MSDS

Name: 2-Bromo-1-(4-chlorophenyl)-2-phenylethan-1-one 95+% Material Safety Data Sheet
Synonym:
CAS: 1889-78-7
Section 1 - Chemical Product MSDS Name:2-Bromo-1-(4-chlorophenyl)-2-phenylethan-1-one 95+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1889-78-7 2-Bromo-1-(4-chlorophenyl)-2-phenyleth 95+% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1889-78-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 67 - 69 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H10BrClO
Molecular Weight: 310

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, bases, amines.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1889-78-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromo-1-(4-chlorophenyl)-2-phenylethan-1-one - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1889-78-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1889-78-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1889-78-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C:Corrosive
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
HS Code 2914700090

 Synthetic Route

~99%

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure

2-bromo-1-(4-ch...

CAS#:1889-78-7

Literature: Gopidas, K.R.; Lohray, B.B.; Rajadurai, S.; Das, P.K.; George, M.V. Journal of Organic Chemistry, 1987 , vol. 52, # 13 p. 2831 - 2838

~%

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure

2-bromo-1-(4-ch...

CAS#:1889-78-7

Literature: Jenkins Journal of the American Chemical Society, 1934 , vol. 56, p. 682

~%

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure

2-bromo-1-(4-ch...

CAS#:1889-78-7

Literature: Jenkins Journal of the American Chemical Society, 1934 , vol. 56, p. 682

~%

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure

2-bromo-1-(4-ch...

CAS#:1889-78-7

Literature: Schwenker; Guo Archiv der Pharmazie, 1993 , vol. 326, # 1 p. 45 - 50

~%

2-bromo-1-(4-chlorophenyl)-2-phenylethanone Structure

2-bromo-1-(4-ch...

CAS#:1889-78-7

Literature: Schwenker; Guo Archiv der Pharmazie, 1993 , vol. 326, # 1 p. 45 - 50

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

 Synonyms

1-(4-chlorophenyl)-2-bromo-2-phenylethanone
BB_SC-0155
2-bromo-1-(4-chlorophenyl)-2-phenylethan-1-one
2-bromo-1-(4-chlorophenyl)-2-phenyl ethanone