Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

Modify Date: 2024-01-01 21:53:38

Benzylidenebis(tricyclohexylphosphine)dichlororuthenium Structure
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium structure
Common Name Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
CAS Number 172222-30-9 Molecular Weight 800.696
Density N/A Boiling Point 383.4ºC at 760 mmHg
Molecular Formula C44H38Cl2P2Ru Melting Point 153ºC (dec.)
MSDS Chinese USA Flash Point 195.6ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 383.4ºC at 760 mmHg
Melting Point 153ºC (dec.)
Molecular Formula C44H38Cl2P2Ru
Molecular Weight 800.696
Flash Point 195.6ºC
Exact Mass 800.086975
PSA 27.18000
LogP 10.59820
Vapour Pressure 9.7E-06mmHg at 25°C
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H228-H315-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR 1325
WGK Germany 3
Packaging Group
HS Code 28439000

 Articles15

More Articles
Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).

Angew. Chem. Int. Ed. Engl. 45 , 3760, (2006)

Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes.

J. Org. Chem. 62 , 7310, (1997)

Ruthenium alkylidene 1 and molybdenum alkylidene 2 have been utilized in the ring-closing metathesis (RCM) of dienes containing gem-disubstituted olefins to yield tri- and tetrasubstituted cyclic olef...

 Synonyms

Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
MFCD01090946
GRUBBS CATALYST
Grubbs catalyst,1st Generation
ruthenium phosphine
Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride
Bis(tricyclohexylphosphine)benzylidene ruthenium (IV) dichloride
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