Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
Names
[ CAS No. ]:
172222-30-9
[ Name ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
[Synonym ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
MFCD01090946
GRUBBS CATALYST
Grubbs catalyst,1st Generation
ruthenium phosphine
Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride
Bis(tricyclohexylphosphine)benzylidene ruthenium (IV) dichloride
Chemical & Physical Properties
[ Boiling Point ]:
383.4ºC at 760 mmHg
[ Melting Point ]:
153ºC (dec.)
[ Molecular Formula ]:
C44H38Cl2P2Ru
[ Molecular Weight ]:
800.696
[ Flash Point ]:
195.6ºC
[ Exact Mass ]:
800.086975
[ PSA ]:
27.18000
[ LogP ]:
10.59820
[ Vapour Pressure ]:
9.7E-06mmHg at 25°C
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H228-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
1325
[ WGK Germany ]:
3
[ Packaging Group ]:
Ⅱ
[ HS Code ]:
28439000
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Rev. 110 , 1746, (2010)
Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).
Angew. Chem. Int. Ed. Engl. 45 , 3760, (2006)
Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes.
J. Org. Chem. 62 , 7310, (1997)
Ruthenium alkylidene 1 and molybdenum alkylidene 2 have been utilized in the ring-closing metathesis (RCM) of dienes containing gem-disubstituted olefins to yield tri- and tetrasubstituted cyclic olef...