DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
Names
[ CAS No. ]:
203714-71-0
[ Name ]:
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
[Synonym ]:
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II)
Hoveyda-Grubbs Catalyst 1st Generation
Hoveyda-Grubbs first generation catalyst
Phosphine, tricyclohexyl-, compd. with dichloro[[2-(1-methylethoxy)phenyl]methylene]ruthenium (1:1)
Dichloro(2-isopropoxybenzylidene)ruthenium - tricyclohexylphosphine (1:1)
MFCD03453042
dichloro(tricyclohexylphosphine)-(o-isopropoxy-phenylmethylene)ruthenium(II)
Chemical & Physical Properties
[ Boiling Point ]:
383.4ºC at 760 mmHg
[ Melting Point ]:
195-197ºC(lit.)
[ Molecular Formula ]:
C28H45Cl2OPRu
[ Molecular Weight ]:
600.606
[ Flash Point ]:
195.6ºC
[ Exact Mass ]:
600.162903
[ PSA ]:
22.82000
[ LogP ]:
10.01880
[ Vapour Pressure ]:
9.7E-06mmHg at 25°C
[ Storage condition ]:
2~8°C
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H228
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
F+
[ RIDADR ]:
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Rev. 110 , 1746, (2010)
Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.
Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)
The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...
The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story.Acc. Chem. Res. 34 , 18, (2001)
In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advance...