Trost ligand
Trost ligand structure
|
Common Name | Trost ligand | ||
|---|---|---|---|---|
| CAS Number | 172138-95-3 | Molecular Weight | 324.377 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 663.4±50.0 °C at 760 mmHg | |
| Molecular Formula | C18H20N4O2 | Melting Point | 170ºC | |
| MSDS | Chinese USA | Flash Point | 355.0±30.1 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | N-[(1S,2S)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 663.4±50.0 °C at 760 mmHg |
| Melting Point | 170ºC |
| Molecular Formula | C18H20N4O2 |
| Molecular Weight | 324.377 |
| Flash Point | 355.0±30.1 °C |
| Exact Mass | 324.158630 |
| PSA | 83.98000 |
| LogP | 0.77 |
| Vapour Pressure | 0.0±2.0 mmHg at 25°C |
| Index of Refraction | 1.610 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xn: Harmful; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-36/37/39 |
| RIDADR | NONH for all modes of transport |
|
~84%
Trost ligand CAS#:172138-95-3 |
| Literature: Conlon, David A.; Yasuda, Nobuyoshi Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 137 - 138 |
|
~79%
Trost ligand CAS#:172138-95-3 |
| Literature: Morimoto, Hiroyuki; Fujiwara, Risa; Shimizu, Yuhei; Morisaki, Kazuhiro; Ohshima, Takashi Organic Letters, 2014 , vol. 16, # 7 p. 2018 - 2021 |
|
~74%
Trost ligand CAS#:172138-95-3 |
| Literature: Hermange, Philippe; Lindhardt, Anders T.; Taaning, Rolf H.; Bjerglund, Klaus; Lupp, Daniel; Skrydstrup, Troels Journal of the American Chemical Society, 2011 , vol. 133, # 15 p. 6061 - 6071 |
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Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
Chem. Rev. 96 , 395, (1996)
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Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
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Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)
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| (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane |
| Trost ligand |
| N,N'-(1S,2S)-1,2-Cyclohexanediyldi(2-pyridinecarboxamide) |
| 2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis- |
| (1S,2S)-N,N′-1,2-Cyclohexanediylbis(2-pyridinecarboxamide) |
| (S,S)-DACH-pyridyl Trost ligand |
| MFCD02684543 |