4,4'-Bis(chloromethyl)biphenyl

Modify Date: 2024-01-02 12:08:08

4,4'-Bis(chloromethyl)biphenyl Structure
4,4'-Bis(chloromethyl)biphenyl structure
Common Name 4,4'-Bis(chloromethyl)biphenyl
CAS Number 1667-10-3 Molecular Weight 251.151
Density 1.2±0.1 g/cm3 Boiling Point 380.0±37.0 °C at 760 mmHg
Molecular Formula C14H12Cl2 Melting Point 126 °C (dec.)(lit.)
MSDS Chinese USA Flash Point 196.3±19.8 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 4,4'-Bis(chloromethyl)-1,1'-biphenyl
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 380.0±37.0 °C at 760 mmHg
Melting Point 126 °C (dec.)(lit.)
Molecular Formula C14H12Cl2
Molecular Weight 251.151
Flash Point 196.3±19.8 °C
Exact Mass 250.031601
LogP 4.51
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.585

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S26-S27-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 3
Hazard Class 8.0
HS Code 2903999090

 Synthetic Route

~89%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Journal of the Iranian Chemical Society, , vol. 8, # 1 p. 131 - 141

~0%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Journal of Organic Chemistry, , vol. 56, # 5 p. 1747 - 1758

~84%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Russian Journal of General Chemistry, , vol. 83, # 2 p. 329 - 335 Zh. Obshch. Khim., , vol. 83, # 2 p. 275 - 281,7

~%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Journal of the Chemical Society. Perkin Transactions 2, , # 4 p. 669 - 675

~%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Chemische Berichte, , vol. 32, p. 1053

~%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Journal of the Chemical Society, , vol. 117, p. 525

~%

4,4'-Bis(chloromethyl)biphenyl Structure

4,4'-Bis(chloro...

CAS#:1667-10-3

Literature: Chemische Berichte, , vol. 32, p. 1053

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Detail
Literature: Chemische Berichte, , vol. 66, p. 1471,1474

 Customs

HS Code 2903999090
Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
Esterification of sodium 4-hydroxybenzoate by ultrasound-assisted solid-liquid phase-transfer catalysis using dual-site phase-transfer catalyst.

Ultrason. Sonochem. 21(1) , 395-400, (2014)

The catalytic esterification of sodium 4-hydroxybenzoate with benzyl bromide by ultrasound-assisted solid-liquid phase-transfer catalysis (U-SLPTC) was investigated using the novel dual-site phase-tra...

Pyrolytic carbon from an aromatic precursor and its application as a counter electrode in dye-sensitized solar cells.

Chemistry 17(4) , 1358-64, (2011)

Pyrolytic carbon thin films were deposited on quartz plates through a chemical vapor deposition process, by using a biphenyl precursor, 4,4'-bis(chloromethyl-1,1'-biphenyl). The pyrolytic carbons were...

Reaction of 4, 4'-bis (chloromethyl)-1, 1'-biphenyl and phenol in two-phase medium via phase-transfer catalysis. Wang M-L and Lee Z-F.

J. Mol. Catal. A: Chem. 264(1) , 119-27, (2007)

 Synonyms

4,4′-Bis(chloromethyl)biphenyl
1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene
4,4'-Bis(chloromethyl)-1,1'-biphenyl
EINECS 216-784-4
1,1'-Biphenyl, 4,4'-bis(chloromethyl)-
4,4'-Bis(chloromethyl)biphenyl
MFCD00674019
4,4-Bis(Chloromethyl)Biphenyl
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