tert-butyl (4-bromophenyl)carbamate

Modify Date: 2024-01-04 22:17:13

tert-butyl (4-bromophenyl)carbamate Structure
tert-butyl (4-bromophenyl)carbamate structure
Common Name tert-butyl (4-bromophenyl)carbamate
CAS Number 131818-17-2 Molecular Weight 272.138
Density 1.4±0.1 g/cm3 Boiling Point 281.1±23.0 °C at 760 mmHg
Molecular Formula C11H14BrNO2 Melting Point 103-106 °C(lit.)
MSDS Chinese USA Flash Point 123.8±22.6 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name tert-butyl n-(4-bromophenyl)-carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 281.1±23.0 °C at 760 mmHg
Melting Point 103-106 °C(lit.)
Molecular Formula C11H14BrNO2
Molecular Weight 272.138
Flash Point 123.8±22.6 °C
Exact Mass 271.020782
PSA 38.33000
LogP 4.16
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.570

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2924299090

 Synthetic Route

~97%

tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Chankeshwara, Sunay V.; Chakraborti, Asit K. Synthesis, 2006 , # 16 p. 2784 - 2788

~82%

tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Isley, Nicholas A.; Dobarco, Sebastian; Lipshutz, Bruce H. Green Chemistry, 2014 , vol. 16, # 3 p. 1480 - 1488

~69%

tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Nielsen, Simon Dalsgaard; Smith, Garrick; Begtrup, Mikael; Kristensen, Jesper L. European Journal of Organic Chemistry, 2010 , # 19 p. 3704 - 3710

~96%

tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Augustine, John Kallikat; Bombrun, Agnes; Mandal, Ashis Baran; Alagarsamy, Padma; Atta, Rajendra Nath; Selvam, Panneer Synthesis, 2011 , # 9 art. no. Z17611SS, p. 1477 - 1483

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tert-butyl (4-bromophenyl)carbamate Structure

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CAS#:131818-17-2

Literature: US5484786 A1, ;

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tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Organic and Biomolecular Chemistry, , vol. 12, # 14 p. 2172 - 2175

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tert-butyl (4-bromophenyl)carbamate Structure

tert-butyl (4-b...

CAS#:131818-17-2

Literature: Organic and Biomolecular Chemistry, , vol. 12, # 14 p. 2172 - 2175

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles2

More Articles
Differentiation between partial agonists and neutral 5-HT1B antagonists by chemical modulation of 3-[3-(N,N-dimethylamino)propyl]-4-hydroxy- N-[4-(pyridin-4-yl)phenyl]benzamide (GR-55562).

J. Med. Chem. 40 , 3542-3550, (1997)

The synthesis and binding affinity at cloned h5-HT1D, h5-HT1D, and h5-HT1A receptors of 3-[3-(N,N-dimethylamino)propyl]-4-hydroxy- N-[4-(pyridin-4-yl)phenyl]benzamide (2, GR-55562) and four O-methylat...

Coutts IGC, et al.

Tetrahedron Lett. 38 , 5563, (1997)

 Synonyms

4-Bromoaniline,N-Boc Protected
tert-butyl N-(4-bromophenyl)carbamate
MFCD01006612
2-Methyl-2-propanyl (4-bromophenyl)carbamate
tert-butyl (4-bromophenyl)carbamate
N-BOC-4-bromoaniline
Carbamic acid, N-(4-bromophenyl)-, 1,1-dimethylethyl ester