Dichloro(dicyclopentadienyl)platinum(II)

Modify Date: 2024-01-06 21:32:35

Dichloro(dicyclopentadienyl)platinum(II) Structure
Dichloro(dicyclopentadienyl)platinum(II) structure
Common Name Dichloro(dicyclopentadienyl)platinum(II)
CAS Number 12083-92-0 Molecular Weight 398.18600
Density N/A Boiling Point 170ºC at 760mmHg
Molecular Formula C10H12Cl2Pt Melting Point 220-222°C (lit.)
MSDS N/A Flash Point 46.8ºC

 Names

Name dichloro(dicyclopentadienyl)platinum(ii)
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 170ºC at 760mmHg
Melting Point 220-222°C (lit.)
Molecular Formula C10H12Cl2Pt
Molecular Weight 398.18600
Flash Point 46.8ºC
Exact Mass 396.99600
LogP 3.76110
Vapour Pressure 1.99mmHg at 25°C

 MSDS


Section 1: Product Identification
Chemical Name:Dichloro(dicyclopentadienyl)platinum (II), 99%
CAS Registry Number:12083-92-0
Formula:C10H12PtCl2
EINECS Number:None
Chemical Family:metallocene
Synonym:dicyclopentadienylplatinum dichloride

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound12083-92-0100%1mg/m3(as-Pt)no data

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to skin, eyes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, and vomiting.
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
Acute Health Affects:
and running of the nose. Skin exposure may lead to dermatitis.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:off-white pwdr.
Molecular Weight:398.19
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents, halogens, and active metals
Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen chloride, organic fumes, and platinum salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Not regulated by Title 313.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39

 Synthetic Route

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Dichloro(dicyclopentadienyl)platinum(II) Structure

Dichloro(dicycl...

CAS#:12083-92-0

Literature: Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M. Organometallics, 1987 , vol. 6, p. 1211 - 1218

~%

Dichloro(dicyclopentadienyl)platinum(II) Structure

Dichloro(dicycl...

CAS#:12083-92-0

Literature: Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M. Organometallics, 1987 , vol. 6, p. 1211 - 1218

~%

Dichloro(dicyclopentadienyl)platinum(II) Structure

Dichloro(dicycl...

CAS#:12083-92-0

Literature: Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M. Organometallics, 1987 , vol. 6, p. 1211 - 1218

~%

Dichloro(dicyclopentadienyl)platinum(II) Structure

Dichloro(dicycl...

CAS#:12083-92-0

Literature: Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M. Organometallics, 1987 , vol. 6, p. 1211 - 1218

~%

Dichloro(dicyclopentadienyl)platinum(II) Structure

Dichloro(dicycl...

CAS#:12083-92-0

Literature: Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M. Organometallics, 1987 , vol. 6, p. 1211 - 1218

 Synonyms

[Pt(dicyclopentadiene)Cl2]
Bis-(cyclopentadienyl)-platinum dichloride
Platinum,dichloro(3A,4,7,7A-tetrahydro-4,7-methanoindene)
(dicyclopentadiene)platinum(II) chloride