Phenol,4-chloro-2,6-dimethyl-

Modify Date: 2024-01-06 18:26:15

Phenol,4-chloro-2,6-dimethyl- Structure
Phenol,4-chloro-2,6-dimethyl- structure
Common Name Phenol,4-chloro-2,6-dimethyl-
CAS Number 1123-63-3 Molecular Weight 156.60900
Density 1.183 g/cm3 Boiling Point 241.6ºC at 760 mmHg
Molecular Formula C8H9ClO Melting Point 80-85 °C
MSDS N/A Flash Point 99.9ºC

 Names

Name 4-chloro-2,6-dimethylphenol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.183 g/cm3
Boiling Point 241.6ºC at 760 mmHg
Melting Point 80-85 °C
Molecular Formula C8H9ClO
Molecular Weight 156.60900
Flash Point 99.9ºC
Exact Mass 156.03400
PSA 20.23000
LogP 2.66240
Vapour Pressure 0.0229mmHg at 25°C
Index of Refraction 1.558

 MSDS

Name: 4-Chloro-2 6-Dimethylphenol Material Safety Data Sheet
Synonym: None Known
CAS: 1123-63-3
Section 1 - Chemical Product MSDS Name:4-Chloro-2 6-Dimethylphenol Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1123-63-3 4-Chloro-2,6-Dimethylphenol ca. 100 214-376-0
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Vacuum or sweep up material and place into a suitable, dry disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1123-63-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 81 - 83 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H9ClO
Molecular Weight: 156.61

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acid chlorides, acid anhydrides, bases, steel, copper.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1123-63-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Chloro-2,6-Dimethylphenol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1123-63-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1123-63-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1123-63-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S37/39-S26
HS Code 2908199090

 Synthetic Route

~49%

Phenol,4-chloro-2,6-dimethyl- Structure

Phenol,4-chloro...

CAS#:1123-63-3

Detail
Literature: Journal of the Chemical Society, Chemical Communications, , # 23 p. 1617 - 1619

~%

Phenol,4-chloro-2,6-dimethyl- Structure

Phenol,4-chloro...

CAS#:1123-63-3

Literature: Molecular Crystals and Liquid Crystals (1969-1991), , vol. 96, p. 57 - 70

~%

Phenol,4-chloro-2,6-dimethyl- Structure

Phenol,4-chloro...

CAS#:1123-63-3

Literature: Journal of Applied Chemistry, , vol. 5, p. 289,293

~4%

Phenol,4-chloro-2,6-dimethyl- Structure

Phenol,4-chloro...

CAS#:1123-63-3

Detail
Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2617 - 2625

~44%

Phenol,4-chloro-2,6-dimethyl- Structure

Phenol,4-chloro...

CAS#:1123-63-3

Detail
Literature: Journal of Organic Chemistry, , vol. 51, # 2 p. 174 - 179

 Customs

HS Code 2908199090
Summary HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

 Synonyms

4-Chloro-2,6-xylenol
4-Chlor-2,6-dimethyl-phenol
p-chloro-vic-m-2-xylenol
MFCD00020138
Phenol,4-chloro-2,6-dimethyl
2,6-dimethyl-4-chlorophenol
4-chloro-2,6-dimethyl-phenol
5-Chlor-2-hydroxy-m-xylol
EINECS 214-376-0