2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside

Modify Date: 2024-01-02 05:32:44

2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside Structure
2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside structure
Common Name 2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside
CAS Number 10139-02-3 Molecular Weight 342.301
Density 1.5±0.1 g/cm3 Boiling Point 685.2±55.0 °C at 760 mmHg
Molecular Formula C14H18N2O8 Melting Point 264ºC
MSDS USA Flash Point 368.2±31.5 °C

 Use of 2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside


4-Nitrophenyl N-acetyl-α-D-glucosaminide is a 4-nitrophenyl- conjugated substrate for determining the enzymatic specificity[1].

 Names

Name P-NITROPHENYL 2-ACETAMIDO-2-DEOXY-α-D-GLUCOPYRANOSIDE
Synonym More Synonyms

  Biological Activity

Description 4-Nitrophenyl N-acetyl-α-D-glucosaminide is a 4-nitrophenyl- conjugated substrate for determining the enzymatic specificity[1].
Related Catalog
References

[1]. Daniel Garrido, et al. Release and utilization of N-acetyl-D-glucosamine from human milk oligosaccharides by Bifidobacterium longum subsp. Infantis. Anaerobe. 2012 Aug;18(4):430-5.  

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 685.2±55.0 °C at 760 mmHg
Melting Point 264ºC
Molecular Formula C14H18N2O8
Molecular Weight 342.301
Flash Point 368.2±31.5 °C
Exact Mass 342.106323
PSA 154.07000
LogP -0.30
Vapour Pressure 0.0±2.2 mmHg at 25°C
Index of Refraction 1.620
Storage condition −20°C

 MSDS

Name: 4-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside 99% Material Safety Data Sheet
Synonym: None
CAS: 10139-02-3
Section 1 - Chemical Product MSDS Name:4-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside 99% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10139-02-3 4-Nitrophenyl-2-acetamido-2-deoxy-alph 99.0 233-392-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Deep freeze (below -20C). Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10139-02-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 264 deg C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H18N2O8
Molecular Weight: 342.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10139-02-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Nitrophenyl-2-acetamido-2-deoxy-alpha-D-glucopyranoside, 9 - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 10139-02-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10139-02-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10139-02-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25
RIDADR NONH for all modes of transport
WGK Germany 3

 Articles21

More Articles
Syntheses of the 3- and 4-thio analogues of 4-nitrophenyl 2-acetamido-2-deoxy-beta-D-gluco- and galactopyranoside.

Carbohydr. Res. 342(15) , 2212-22, (2007)

The syntheses of 4-nitrophenyl beta-glycosides of the 3-thio and 4-thio analogues of the two principal 2-acetamido-2-deoxy-hexoses found in living systems, GlcNAc and GalNAc, are described. While synt...

Chitin oligosaccharide synthesis by rhizobia and zebrafish embryos starts by glycosyl transfer to O4 of the reducing-terminal residue.

Biochemistry 38(13) , 4045-52, (1999)

Lipochitin oligosaccharides are organogenesis-inducing signal molecules produced by rhizobia to establish the formation of nitrogen-fixing root nodules in leguminous plants. Chitin oligosaccharide bio...

Purification and characterization of beta-N-acetylhexosaminidase from Trichoderma harzianum.

Agric. Biol. Chem. 55(11) , 2817-23, (1991)

beta-N-Acetylhexosaminidase was produced by Trichoderma harzianum cultivated with chitin as the growth substrate. The enzyme was purified 13.2-fold to homogeneity by ultrafiltration and sequential chr...

 Synonyms

2-Nitrophenyl 2-acetamido-2-deoxyhexopyranoside
Hexopyranoside, 2-nitrophenyl 2-(acetylamino)-2-deoxy-
4-Nitrophenyl N-acetyl-1-thio-|A-D-glucosaminide
MFCD00006592
p-Nitrophenyl 2-Acetamido-2-deoxy-Alpha-D-glucopyranoside
EINECS 233-392-9
p-nitrophenyllacto-N-biose
p-Nitrophenyl 2-acetamido-2-deoxy-1-thio-|A-D-glucopyranoside