41918-08-5

41918-08-5 structure
41918-08-5 structure

Name Ethyl (S)-(-)-2-methoxypropionate
Synonyms Ethyl (2S)-2-methoxypropanoate
Density 0.959g/cm3
Boiling Point 160ºC at 760 mmHg
Molecular Formula C6H12O3
Molecular Weight 132.15800
Flash Point 49.9ºC
Exact Mass 132.07900
PSA 35.53000
LogP 0.58440
Appearance Liquid | Clear colorless to slightly yellow
Index of Refraction 1.398
Name: Ethyl (S)-(-)-2-Methoxypropionate Material Safety Data Sheet
Synonym: None Known
CAS: 41918-08-5
Section 1 - Chemical Product MSDS Name:Ethyl (S)-(-)-2-Methoxypropionate Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
41918-08-5 Ethyl (S)-(-)-2-Methoxypropionate ca. 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 41918-08-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H12O3
Molecular Weight: 132.16

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
No specific conditions to avoid noted.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 41918-08-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl (S)-(-)-2-Methoxypropionate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 41918-08-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 41918-08-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 41918-08-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S24/25
HS Code 2918990090

~93%

41918-08-5 structure

41918-08-5

Literature: Barrett, Anthony G. M.; Braddock, D. Christopher; Christian, Paul W. N.; Pilipauskas, Daniel; White, Andrew J. P.; Williams, David J. Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5818 - 5823

~48%

41918-08-5 structure

41918-08-5

Literature: Jamieson, Andrew G.; Sutherland, Andrew Organic and Biomolecular Chemistry, 2005 , vol. 3, # 5 p. 735 - 736

~%

41918-08-5 structure

41918-08-5

Literature: Weber; Kreuzig; Bahadir Chemosphere, 1997 , vol. 35, # 1-2 p. 13 - 20

~%

41918-08-5 structure

41918-08-5

Literature: Kobayashi, Kimiko; Kato, Takayuki; Unno, Masafumi; Masuda, Shinji Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 6 p. 1393 - 1401

~%

41918-08-5 structure

41918-08-5

Literature: Stevens; Deans Canadian Journal of Research, Section B: Chemical Sciences, 1939 , vol. 17, p. 290

~%

41918-08-5 structure

41918-08-5

Literature: Brookhart, Maurice; Liu, Yumin; Goldman, Emma W.; Timmers, Debra A.; Williams, Gregory D. Journal of the American Chemical Society, 1991 , vol. 113, # 3 p. 927 - 939

~%

41918-08-5 structure

41918-08-5

Literature: Terfort, Andreas; Brunner, Henri Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 12 p. 1467 - 1479
HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%