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108-87-2

108-87-2 structure
108-87-2 structure

Name Methylcyclohexane
Synonyms Methylcyclohexane
Hexahydrotoluene
EINECS 203-624-3
MFCD00001497
METHYL CYCLOHEXANE
Density 0.8±0.1 g/cm3
Boiling Point 101.1±3.0 °C at 760 mmHg
Melting Point -126.3ºC
Molecular Formula C7H14
Molecular Weight 98.186
Flash Point -3.9±0.0 °C
Exact Mass 98.109550
LogP 3.88
Vapour density 3.4 (vs air)
Vapour Pressure 41.1±0.1 mmHg at 25°C
Index of Refraction 1.426
Stability Stable. Very flammable. Incompatible with strong oxidizing agents.
Water Solubility 0.1 g/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GV6125000
CHEMICAL NAME :
Cyclohexane, methyl-
CAS REGISTRY NUMBER :
108-87-2
LAST UPDATED :
199712
DATA ITEMS CITED :
35
MOLECULAR FORMULA :
C7-H14
MOLECULAR WEIGHT :
98.21
WISWESSER LINE NOTATION :
L6TJ A1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,82,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
41500 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,82,1982
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Gastrointestinal - hypermotility, diarrhea
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 25,199,1943
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
15227 ppm/1H
TOXIC EFFECTS :
Behavioral - general anesthetic Behavioral - convulsions or effect on seizure threshold Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 25,323,1943
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>86700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 25,199,1943 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
10054 ppm/6H/2W-I
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 25,323,1943 *** REVIEWS *** ACGIH TLV-TWA 1610 mg/m3 (400 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 500 ppm (2000 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,162,1971 OSHA PEL (Gen Indu):8H TWA 500 ppm (2000 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 500 ppm (2000 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 500 ppm (2000 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 500 ppm (2000 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 400 ppm (1600 mg/m3) JAN 1993 OEL-BELGIUM:TWA 400 ppm (1610 mg/m3) JAN 1993 OEL-DENMARK:TWA 400 ppm (1600 mg/m3) JAN 1993 OEL-FINLAND:TWA 400 ppm (1600 mg/m3);STEL 500 ppm (2000 mg/m3) JAN 1993 OEL-FRANCE:TWA 400 ppm (1600 mg/m3) JAN 1993 OEL-GERMANY:TWA 500 ppm (2000 mg/m3) JAN 1993 OEL-JAPAN:TWA 400 ppm (1600 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 400 ppm (1600 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 500 ppm (2000 mg/m3) JAN 1993 OEL-POLAND:TWA 500 mg/m3 JAN 1993 OEL-RUSSIA:TWA 400 ppm;STEL 50 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 400 ppm (1600 mg/m3);STEL 800 ppm JAN 1993 OEL-TURKEY:TWA 500 ppm (2000 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 400 ppm (1600 mg/m3);STEL 500 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO METHYLCYCLOHEXANE-air:10H TWA 400 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 47030 No. of Facilities: 1733 (estimated) No. of Industries: 11 No. of Occupations: 9 No. of Employees: 6292 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 47030 No. of Facilities: 1175 (estimated) No. of Industries: 12 No. of Occupations: 11 No. of Employees: 10076 (estimated) No. of Female Employees: 14 (estimated)
Symbol GHS02 GHS07 GHS08 GHS09
GHS02, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H225-H304-H315-H336-H410
Precautionary Statements P210-P301 + P310-P331-P370 + P378-P403 + P235
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;Xn:Harmful;N:Dangerousfortheenvironment;
Risk Phrases R11;R38;R51/53;R65;R67
Safety Phrases S16-S33-S61-S62-S9
RIDADR UN 2296
WGK Germany 2
RTECS GV6125000
Packaging Group II
Hazard Class 3.0
HS Code 2910200000
Precursor  2

DownStream  0

HS Code 2902199090
Summary 2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%