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760-93-0

760-93-0 structure
760-93-0 structure
  • Name: Methacrylic anhydride
  • Chemical Name: Methacrylic anhydride
  • CAS Number: 760-93-0
  • Molecular Formula: C8H10O3
  • Molecular Weight: 154.163
  • Catalog: Research Areas Others
  • Create Date: 2018-02-07 08:00:00
  • Modify Date: 2024-01-02 16:48:19
  • Methacrylic anhydride is a typical polymerizable 1,6-diolefin. Methacrylic anhydride can form a soluble csyclopolymer by free-radical initiation. Methacrylic anhydride can spontaneously polymerize through the vinyl group and justifies the use of 2-6-di-tert-butyl4-methylphenol as an inhibitor[1][2].

Name Methacrylic anhydride
Synonyms 2-methylprop-2-enoyl 2-methylprop-2-enoate
EINECS 212-084-8
MFCD00008586
Description Methacrylic anhydride is a typical polymerizable 1,6-diolefin. Methacrylic anhydride can form a soluble csyclopolymer by free-radical initiation. Methacrylic anhydride can spontaneously polymerize through the vinyl group and justifies the use of 2-6-di-tert-butyl4-methylphenol as an inhibitor[1][2].
Related Catalog
References

[1]. Jesse C. H. Hwa, et al. Copolymerization of methacrylic anhydride with vinyl monomers. Journal of Polymer Science. November 1961, 55(161):197-213.

[2]. F. Becquart, et al. Functionalization of a poly(vinyl alcohol) in the solid state with a swelling agent by methacrylic anhydride. Polymer Chemistry. 1 April 2004, 42(7):1618-1629.

Density 1.0±0.1 g/cm3
Boiling Point 202.3±0.0 °C at 760 mmHg
Melting Point -20°C
Molecular Formula C8H10O3
Molecular Weight 154.163
Flash Point 84.4±0.0 °C
Exact Mass 154.062988
PSA 43.37000
LogP 1.82
Vapour Pressure 0.3±0.4 mmHg at 25°C
Index of Refraction 1.443
Stability Stable. Flammable. Moisture-sensitive.

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OZ5700000
CHEMICAL NAME :
Methacrylic anhydride
CAS REGISTRY NUMBER :
760-93-0
BEILSTEIN REFERENCE NO. :
1761982
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C8-H10-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
450 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,80,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302 + H332-H315-H317-H318-H335
Precautionary Statements P261-P280-P301 + P312 + P330-P305 + P351 + P338 + P310
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful;
Risk Phrases R20;R37/38;R41
Safety Phrases S26-S39
RIDADR UN 3265 8/PG 2
WGK Germany 1
RTECS OZ5700000
Packaging Group II
Hazard Class 8
HS Code 2916209090
HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%