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7650-89-7

7650-89-7 structure
7650-89-7 structure

Name Tribenzylphosphine
Synonyms tribenzylphosphane
MFCD00014439
EINECS 231-608-6
Boiling Point 183-185°C/0.2mm
Melting Point 96-101 °C(lit.)
Molecular Formula C21H21P
Molecular Weight 304.36500
Flash Point 183-185°C/0.2mm
Exact Mass 304.13800
PSA 13.59000
LogP 6.06890

Section 1: Product Identification
Chemical Name:Tribenzylphosphine, 98%
CAS Registry Number:7650-89-7
Formula:C21H21P
EINECS Number:231-608-6
Chemical Family:organophosphorus ligand
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound7650-89-7100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:dry chemical, carbon dioxide, water, or foam.
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIn a fire material may emit toxic organic fumes, carbon monoxide, carbon dioxide, and phosphorous pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spillage in areas not adequately ventilated may require evacuation of area. Emergency response teams will
Spill and Leak Procedures:require self contained breathing apparatus. Small spills may be adsorbed into diatomaceous earth, sand, or
other suitable adsorbents, and swept up.

SECTION 7: Handling and Storage
Store in a cool, dry, area away from heat. Material must be handled and stored under an inert atmosphere of
Handling and Storage:
nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material has a pungent odor and may form a fine dust. Always handle material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material has a pungent odor and may form a fine dust. Always handle material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:304.37
Melting Point:96-101°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:pungent odor
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with air
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and phosphorus pentoxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases S26
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS SZ3865000

~59%

7650-89-7 structure

7650-89-7

Literature: Landaeta, Vanessa R.; Peruzzini, Maurizio; Herrera, Veronica; Bianchini, Claudio; Sanchez-Delgado, Roberto A.; Goeta, Andres E.; Zanobini, Fabrizio Journal of Organometallic Chemistry, 2006 , vol. 691, # 5 p. 1039 - 1050

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7650-89-7 structure

7650-89-7

Literature: US4053518 A1, ;

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7650-89-7 structure

7650-89-7

Literature: Russian Journal of General Chemistry, , vol. 67, # 1 p. 149 - 150 Zhurnal Obshchei Khimii, , vol. 67, # 1 p. 155 - 156

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7650-89-7 structure

7650-89-7

Literature: Journal of the Chemical Society, , p. 2835,2839

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7650-89-7

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 32, # 2 p. 553 - 557,542 - 545

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7650-89-7 structure

7650-89-7

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 32, # 2 p. 553 - 557,542 - 545

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Detail
Literature: Russian Journal of General Chemistry, , vol. 67, # 1 p. 149 - 150 Zhurnal Obshchei Khimii, , vol. 67, # 1 p. 155 - 156

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7650-89-7 structure

7650-89-7

Literature: Journal of the Chemical Society, , vol. 58, p. 767 Chemische Berichte, 24 Ref. <1891>,365 Transactions of the Royal Society of Edinburgh 35,573 Transactions of the Royal Society of Edinburgh 35,566,574

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7650-89-7 structure

7650-89-7

Literature: Journal of the Chemical Society, , vol. 58, p. 767 Chemische Berichte, 24 Ref. <1891>,365 Transactions of the Royal Society of Edinburgh 35,573