Name | 1-(4-Methoxyphenyl)cyclopropanecarboxylic acid |
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Synonyms |
1-(4-Methoxyphenyl)cyclopropanecarboxylic acid
1-(4-methoxyphenyl)cyclopropane-1-carboxylic acid EINECS 240-788-5 MFCD00019223 Cyclopropanecarboxylic acid, 1-(4-methoxyphenyl)- 1-(4-Methoxyphenyl)-1-cyclopropanecarboxylic acid Cyclopropanecarboxylicacid, 1-(4-methoxyphenyl)- |
Density | 1.3±0.1 g/cm3 |
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Boiling Point | 347.7±35.0 °C at 760 mmHg |
Melting Point | 127-132 °C |
Molecular Formula | C11H12O3 |
Molecular Weight | 192.211 |
Flash Point | 138.6±19.4 °C |
Exact Mass | 192.078644 |
PSA | 46.53000 |
LogP | 1.46 |
Vapour Pressure | 0.0±0.8 mmHg at 25°C |
Index of Refraction | 1.585 |
Storage condition | Room temperature. |
Synonym:1-(4-Methoxyphenyl)cyclopropane-1-carboxylic aci Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16728-01-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 124.00 - 126.00 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C11H12O3 Molecular Weight: 192.21 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16728-01-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-(4-Methoxyphenyl)-1-cyclopropanecarboxylic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 16728-01-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 16728-01-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16728-01-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Safety Phrases | S24/25 |
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HS Code | 2918990090 |
~77% 16728-01-1 |
Literature: Mndzhoyan, Sh. L.; Tsinker, M. G.; Ovakimyan, A. R.; Ter-Zakharyan, Yu. Z.; Kazaryan, E. V.; Paronikyan, R. V. Pharmaceutical Chemistry Journal, 1980 , vol. 14, # 2 p. 114 - 118 Khimiko-Farmatsevticheskii Zhurnal, 1980 , vol. 14, # 2 p. 40 - 45 |
~62% 16728-01-1 |
Literature: Kirmse, Wolfgang; Rode, Jutta Chemische Berichte, 1986 , vol. 119, # 12 p. 3694 - 3703 |
~% 16728-01-1 |
Literature: Chemische Berichte, , vol. 119, # 12 p. 3694 - 3703 |
~% 16728-01-1 |
Literature: Chemische Berichte, , vol. 119, # 12 p. 3694 - 3703 |
~% 16728-01-1 |
Literature: Pharmaceutical Chemistry Journal, , vol. 14, # 2 p. 114 - 118 Khimiko-Farmatsevticheskii Zhurnal, , vol. 14, # 2 p. 40 - 45 |
Precursor 3 | |
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DownStream 5 | |
HS Code | 2918990090 |
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Summary | 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |