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99105-77-8

99105-77-8 structure
99105-77-8 structure
Name sulcotrione
Synonyms 1,3-Cyclohexanedione, 2-[2-chloro-4-(methylsulfonyl)benzoyl]-
Mikado
SC0051
chlormesulone
2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione
sulcotrione
2-[2-chloro-4-(methanesulfonyl)benzoyl]cyclohexane-1,3-dione
L6V CVTJ BVR BG DSW1
GALLEON
CHLORMESULON
2-(2-chloro-4-methylsulfonylbenzoyl)-cyclohexane-1,3-dione
2-(2-chloro-4-methylsulphonylbenzoyl)cyclohexane-1,3-dione
2-(2-chloro-4-(methylsulfonyl)benzoyl)-1,3-cyclohexanwdione
2-(2-Chlor-4-(methylsulfonyl)-benzoyl)-1,3-cyclohexandion
2-(2-chloro-4-mesylbenzoyl)-cyclohexane-1,3-dione
2-(2-Chloro-4-methanesulfonylbenzoyl)-cyclohexane-1,3-dione
ICIA0051
2-(2-Chloro-4-mesylbenzoyl)cyclohexane-1,3-dione
2-[2-chloro-4-(methylsulfonyl)-benzoyl]-1,3-cyclohexanedione
SULCOTRIONE,MESOTRIONE
Description Sulcotrione is a β-triketone herbicide which can inhibit hydroxyphenylpyruvate dioxygenase (HPPD).
Related Catalog
Target

HPPD[1]

In Vitro The results show that sulcotrione behaves as time-independent reversible inhibitor. Similar results are previously described for natural β-triketones, and for the synthetic β-triketone NTBC. However it is the first time that such behavior is observed using a purified hydroxyphenylpyruvate dioxygenase (HPPD) and a synthetic β-triketone, namely sulcotrione. Inhibition kinetic analysis, performing with 3 hydroxyphenylpyruvate (HPP) and sulcotrione concentrations, show that the apparent KM increasing with sulcotrione concentration. This behavior is consistent with the data present in the literature, describing sulcotrione as a competitive inhibitor of HPPD[1].
Kinase Assay Electrochemical behavior of sulcotrione at 0.2 mg/L is characterized by cyclic voltammetry. Preliminary HPPD inhibition assays are performed by incubating the enzyme during time periods ranging from 2 to 10 min in presence of sulcotrione at differnt concentrations[1].
References

[1]. Rocaboy-Faquet E, et al. A novel amperometric biosensor for ß-triketone herbicides based on hydroxyphenylpyruvatedioxygenase inhibition: A case study for sulcotrione. Talanta. 2016;146:510-6.
Density 1.4±0.1 g/cm3
Boiling Point 574.5±50.0 °C at 760 mmHg
Melting Point 139ºC
Molecular Formula C14H13ClO5S
Molecular Weight 328.768
Flash Point 301.2±30.1 °C
Exact Mass 328.017212
PSA 93.73000
LogP 0.21
Vapour Pressure 0.0±1.6 mmHg at 25°C
Index of Refraction 1.572
Symbol GHS08 GHS09
GHS08, GHS09
Signal Word Warning
Hazard Statements H361-H373-H410
Precautionary Statements P273-P281-P501
Target Organs Kidney
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R43
Safety Phrases S36/37
RIDADR UN 3077 9 / PGIII
HS Code 2930909056
504-02-9 structure

504-02-9

106904-10-3 structure

106904-10-3

~%

99105-77-8 structure

99105-77-8

Literature: WO2003/99409 A1, ; Page 12, 13 ;
53250-83-2 structure

53250-83-2

504-02-9 structure

504-02-9

584-08-7 structure

584-08-7

75-86-5 structure

75-86-5

~%

Detail
Literature: US5318947 A1, ;
HS Code 2930909056
Summary 2930909056 2,6-dichlorobenzothioamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%
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title: CAS No. 99105-77-8 | Chemsrc address: https://www.chemsrc.com/en/baike/330860.html

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