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13820-95-6

13820-95-6 structure
13820-95-6 structure
  • Name: CHLOROPENTAMMINERHODIUM(III) DICHLORIDE
  • Chemical Name: azane,rhodium(3+),trichloride
  • CAS Number: 13820-95-6
  • Molecular Formula: H15Cl3N5Rh
  • Molecular Weight: 294.417
  • Create Date: 2018-05-07 08:00:00
  • Modify Date: 2024-01-03 10:39:07

Name azane,rhodium(3+),trichloride
Synonyms Pentamminechlororhodium dichloride
EINECS 237-505-2
rhodium(3+) chloride ammoniate(1:3:5)
Chloropentaammine rhodium dichloride
MFCD00135665
Chloropentamminerhodium(III) dichloride
Chloropentaamminerhodium(III)
Trichlororhodium pentaammoniate
Pentaamminechlororhodium dichloride
Molecular Formula H15Cl3N5Rh
Molecular Weight 294.417
Exact Mass 292.944794
PSA 16.20000
LogP 3.68800
Vapour Pressure 5990mmHg at 25°C

Section 1: Product Identification
Chemical Name:Chloropentaamminerhodium (III) chloride, 99%
CAS Registry Number:13820-95-6
Formula:[Rh(NH3)5Cl]Cl2
EINECS Number:237-505-2
Chemical Family:metal-ammine complexes
Synonym:Pentaamminechlororhodium (III) dichloride

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13820-95-6100%1 mg/m3 (as Rh)0.1 mg/m3 (as Rh)

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and mucous membranes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
Chronic Health Affects:
may be present.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic and metal oxide fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:golden yellow xtl.
Molecular Weight:294.43
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:slightly soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:active metals
Decomposition Products:hydrogen chloride, ammonia, and rhodium salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi
Safety Phrases S26-S37/39