13434-24-7

13434-24-7 structure
13434-24-7 structure

Name Manganese bis(2-ethylhexanoate)
Synonyms MFCD00058698
2-Ethylhexanoic acid - manganese (2:1)
Hexanoic acid, 2-ethyl-, manganese salt (2:1)
EINECS 236-562-0
Density 0.940 ---0.955 g/cm3
Boiling Point 228ºC at 760 mmHg
Molecular Formula C16H30MnO4
Molecular Weight 343.361
Flash Point 116.6ºC
Exact Mass 343.168121
PSA 52.60000
LogP 4.42060
Water Solubility Soluble in organic solvents. Not miscible or difficult to mix with water.

Section 1: Product Identification
Chemical Name:Manganese (II) 2-ethylhexanoate, 40% solution in mineral spirits (6% Mn)
CAS Registry Number:13434-24-7
Formula:Mn[OOCCH(C2H5)C4H9]2
EINECS Number:none
Chemical Family:metal carboxylate
Synonym:2-Ethylhexanoic acid, manganese +2 salt

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound13434-24-740%0.2mg/m3 (as Mn)5mg/m3 (as Mn)
mineral spirits64475-85-060%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed or inhaled.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Vapor is irritating to the nose, mucous membranes and respiratory tract, and cause drowsiness.
Ingestion:No information available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese
Chronic Health Affects:poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have
shown manganese may decrease fertility in men.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite or other suitable chemical adsorbent. The residue can be swept up
Spill and Leak Procedures:
and properly disposed of.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Handle the material in a ventilated area.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:dark liquid
Molecular Weight:341.35
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:mild organic odor
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable liquid
Hazardous Polymerization:none
Conditions to Avoid:exposure to excessive heat or an ignition source.
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and manganese oxides.

SECTION 11: Toxicological Information
No information available on the title compound. For mineral spirits: Oral (rat); LD50: >34600mg/kg.
RTECS Data:
Inhalation (rat); LC50: >21400mg/m3/hr. Intraperitoneal (rat); LDLo: 8560 mg/kg.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Flammable liquids, N.O.S.
Hazard Class (CFR):3
Additional Hazard Class (CFR):NA
Packaging Group (CFR):III
UN ID Number (CFR):UN# 1993
Shipping Name (IATA):Flammable liquid, N.O.S.
Hazard Class (IATA):3
Additional Hazard Class (IATA):NA
Packaging Group (IATA):III
UN ID Number (IATA):UN# 1993

SECTION 15: Regulatory Information
TSCA:listed on the TSCA inventory
SARA (Title 313):Title compound: See category code N450 for reporting
Second Ingredient:not listed on the TSCA inventory


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xn: Harmful;
Risk Phrases R10
Safety Phrases 16-36/37/39
RIDADR UN 1993
Packaging Group III